TiO2 photocatalytic degradation of PCBs in soil-water systems containing fluoro surfactant.

Abstract:

:Titanium dioxide-mediated photodegradation of Polychlorinated biphenyls (PCBs) in soil/aqueous systems with added fluorinated surfactant was investigated. PCBs can bind tightly to organic matter in the soil, especially in aged, contaminated soil. Experiments showed an effective PCB photocatalytic degradation in mixed systems of soil/clay with anionic fluorinated surfactant FC-143 and TiO2. The FC-143 surfactant is stable in this photochemical process. PCB degradation rates in samples followed the order: spiked clay > spiked soil > Hudson River bank soil. The results suggest that anionic fluorinated surfactant may form semimicelles and/or admicelles on the surface of positively charged TiO2. The hydrophobic surface of TiO2 can provide a nonpolar phase that acts as a partioning medium for hydrophobic PCBs. Therefore, PCBs in soil can be released to the semimicelle and/or admicelle on the TiO2 surface and are effectively photodegraded in a dispersion containing anionic fluorinated surfactant. The combination of surfactant extraction and photooxidation forms the basis for a novel two-stage process for the removal and destruction of PCBs from soil.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Huang Q,Hong CS

doi

10.1016/s0045-6535(99)00492-0

subject

Has Abstract

pub_date

2000-09-01 00:00:00

pages

871-9

issue

6

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(99)00492-0

journal_volume

41

pub_type

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