Deoxyarteannuin B, dihydro-deoxyarteannuin B and trans-5-hydroxy-2-isopropenyl-5-methylhex-3-en-1-ol from Artemisia anuua.

Abstract:

:The amorphane sesquiterpenes, deoxyarteannuin B and dihydro-deoxyarteannuin B, were isolated from Artemisia annua and their structures mainly determined by two-dimensional NMR spectoscopic analyses. The irregular monoterpene, trans-5-hydroxy-2-isopropenyl-5-methylhex-3-en-1-ol, was also characterized in the same way, and its structure was confirmed by synthesis from lavandulol. All of these natural products are suggested to be formed by autoxidation reactions. Full assignments of the 1H and 13C resonances for the known natural products epi-deoxyarteannuin B and isoannulide, determined by the same methodology, are also reported.

journal_name

Phytochemistry

journal_title

Phytochemistry

authors

Sy LK,Brown GD

doi

10.1016/s0031-9422(01)00358-2

subject

Has Abstract

pub_date

2001-12-01 00:00:00

pages

1159-66

issue

8

eissn

0031-9422

issn

1873-3700

pii

S0031-9422(01)00358-2

journal_volume

58

pub_type

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