Isolation and structure elucidation of tetrameric procyanidins from unripe apples (Malus pumila cv. Fuji) by NMR spectroscopy.

Abstract:

:Procyanidins are plant secondary metabolites widely consumed and known to have various physiological functions, but their bioavailability and mechanism of action are still unclear especially for larger oligomers. One of the reasons is scarce information about the detailed structure of oligomeric procyanidins. As for apple, structures of procyanidin components larger than trimers are scarcely known. In this study, 11 tetrameric procyanidins including two known compounds were isolated from unripe apples (Malus pumila cv. Fuji) and identified by NMR spectroscopic analysis and phloroglucinol degradation. As a result, the detailed structural diversity of tetrameric procyanidins in apple was established.

journal_name

Phytochemistry

journal_title

Phytochemistry

authors

Nakashima S,Oda C,Masuda S,Tagashira M,Kanda T

doi

10.1016/j.phytochem.2012.07.011

subject

Has Abstract

pub_date

2012-11-01 00:00:00

pages

144-52

eissn

0031-9422

issn

1873-3700

pii

S0031-9422(12)00333-0

journal_volume

83

pub_type

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