Effect of copper chloride on the emissions of PCDD/Fs and PAHs from PVC combustion.

Abstract:

:The influences of temperature, air flow and the amount of copper chloride upon the types and amount of the toxic emissions such as polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) and polycyclic aromatic hydrocarbons (PAHs) during combustion of polyvinyl chloride (PVC) were investigated. The mechanism concerning the effect of temperature and copper chloride on the PCDD/Fs and PAHs formation was discussed. The results shown that without copper chloride, trace amounts of PCDD/Fs and large amounts of PAHs were found in the emissions from the pure PVC combustion under various combustion conditions. The addition of copper chloride enhanced PCDD/Fs formation, but it seems that the formation of PAHs decreased with increasing amount of copper chloride, and greater total amount of PAHs were produced at the higher temperature under our experimental conditions.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Wang D,Xu X,Zheng M,Chiu CH

doi

10.1016/s0045-6535(02)00020-6

subject

Has Abstract

pub_date

2002-09-01 00:00:00

pages

857-63

issue

8

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(02)00020-6

journal_volume

48

pub_type

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