Abstract：
:Octachlorodibenzo-p-dioxin (OCDD)-added, pretreated fly ash was heated under vacuum at sample temperatures ranging from T(s)=450 to 650 K. The fly ash and liquid nitrogen-cooled trap samples were analyzed for DD/DF through OCDD/DF. The total amounts of DD through OCDD decrease with increasing T(s), which indicates that dechlorination/hydrogenation (DCH) reactions are not the only reaction channels. Reduction of toxic equivalent (TEQ) for PCDDs by more than 99% was achieved in the fly ash by the vacuum heat treatment at T(s)=650 K for 4 h. The total amount of PCDDs and DD detected in the liquid nitrogen-cooled trap relative to that of added OCDD was about 17%, i.e., PCDDs and DD which were adsorbed to the fly ash surfaces can evaporate into the gaseous phase. The difference between the evaporation behavior of PCDDs in the present and the previous studies is discussed in the light of their states of existence.
journal_name
Chemospherejournal_title
Chemosphereauthors
Misaka Y,Abe T,Takeuchi K,Ohba K,Sawabe K,Shobatake Kdoi
10.1016/j.chemosphere.2006.01.079subject
Has Abstractpub_date
2006-10-01 00:00:00pages
419-26issue
3eissn
0045-6535issn
1879-1298pii
S0045-6535(06)00264-5journal_volume
65pub_type
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