Abstract：
:In this study, the complexation of Tb3+ with natural organic matter (NOM) was studied by the method of time-resolved fluorescence spectroscopy. In the presence of NOM, the excitation of Tb3+ was observed in a wide range of wavelengths, for which virtually no excitation of free Tb3+ took place. The pseudo-quantum yield spectra (excitation intensity normalized by corresponding light absorbance values) had a maximum at 282 nm. This indicated that the excitation of NOM-bound Tb3+ proceeds through energy transfer from aromatic groups in NOM. The concentration of the metal-binding sites (C(L)) was determined by titration with Tb3+ and was found to range from 0.21% to 0.83% of total moles of organic carbon. The actual number of the carbon atoms that comprise these functionalities was hypothesized to be at least seven times higher. The C(L) values were well correlated with the reactivity of NOM with chlorine quantified by total organic halogen formation potential and with the contribution of polyhydroxyaromatic moieties determined by pyrolysis-GC/MS method. The correlation of C(L) with the contributions of aromatic and carboxylic moieties in NOM determined by 13C NMR was poor. Based on the data, it was concluded that the metal binding functionalities in NOM are closely associated with halogen attack sites.
journal_name
Chemospherejournal_title
Chemosphereauthors
Li CW,Korshin GVdoi
10.1016/s0045-6535(02)00353-3subject
Has Abstractpub_date
2002-11-01 00:00:00pages
629-36issue
6eissn
0045-6535issn
1879-1298pii
S0045-6535(02)00353-3journal_volume
49pub_type
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