Abstract:
:A facile synthesis of dl-6,10,14-trimethylpentadecan-2-ol (1) a pheromone component of rice moth, Corcyra cephalonica Stainton and 5,9,13-trimethyltetradecanoic acid (2) a component of marine sponge, Cinachyrella alloclada Uliczka, using a common, intermediate, hexahydrofarnesol is accomplished. The salient features for 1 are: Grignard coupling of 5 with allylmagnesium bromide and oxymercuration-demercuration whereas for 2 they are: Knoevenagel condensation and subsequent hydrogenation.
journal_name
Bioorg Med Chemjournal_title
Bioorganic & medicinal chemistryauthors
Rane SS,Chadha MS,Mamdapur VRdoi
10.1016/s0968-0896(00)82149-5subject
Has Abstractpub_date
1993-12-01 00:00:00pages
399-401issue
6eissn
0968-0896issn
1464-3391pii
S0968-0896(00)82149-5journal_volume
1pub_type
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