Competition between phenanthrene, chrysene, and 2,5-dichlorobiphenyl for high-energy adsorption sites in a sediment.

Abstract:

:We determined the maximum amounts of added phenanthrene, chrysene, and 2,5-dichlorobiphenyl sorbed onto high-energy adsorption sites in a sediment on bi-solute experiments. The bi-solute pairs were phenanthrene/chrysene and phenanthrene/2,5-dichlorobiphenyl. On the bi-solute sorption experiments, one solute was introduced and equilibrated with sediment prior to addition of the second solute. The values for the maximum amounts adsorbed onto high-energy sites revealed that, after equilibration of the first solute, still some high-energy sites could be occupied by the second solute. Phenanthrene, chrysene, and 2,5-dichlorobiphenyl seem to share about 30% of the accessible high-energy adsorption sites in the sediment employed.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Morelis S,van den Heuvel H,van Noort PC

doi

10.1016/j.chemosphere.2007.02.041

subject

Has Abstract

pub_date

2007-08-01 00:00:00

pages

2028-32

issue

11

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(07)00278-0

journal_volume

68

pub_type

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