Abstract:
:A practical and efficient disposal method for hydrodechlorination of polychlorinated biphenyls (PCBs) in transformer oil is reported. Transformer oil containing PCBs was treated by nanometric sodium hydride (nano-NaH) and transition metal catalysts. High destruction and removal efficiency (89.8%) can be attained by nano-NaH alone under mild conditions. The process exhibits apparent characteristics of a first order reaction. The reductive ability of nano-NaH was enhanced by the addition of transition metal catalysts. In the presence of TiCl4, 99.9% PCBs was hydrodechlorinated. The complex reducing reagents, Ni(OAc)2+i-PrONa, show extra hydrodechlorinating activity for di-chlorinated biphenyls.
journal_name
Chemospherejournal_title
Chemosphereauthors
Wu W,Xu J,Zhao H,Zhang Q,Liao Sdoi
10.1016/j.chemosphere.2004.11.079subject
Has Abstractpub_date
2005-08-01 00:00:00pages
944-50issue
7eissn
0045-6535issn
1879-1298pii
S0045-6535(04)01164-6journal_volume
60pub_type
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