A practical approach to the degradation of polychlorinated biphenyls in transformer oil.

Abstract:

:A practical and efficient disposal method for hydrodechlorination of polychlorinated biphenyls (PCBs) in transformer oil is reported. Transformer oil containing PCBs was treated by nanometric sodium hydride (nano-NaH) and transition metal catalysts. High destruction and removal efficiency (89.8%) can be attained by nano-NaH alone under mild conditions. The process exhibits apparent characteristics of a first order reaction. The reductive ability of nano-NaH was enhanced by the addition of transition metal catalysts. In the presence of TiCl4, 99.9% PCBs was hydrodechlorinated. The complex reducing reagents, Ni(OAc)2+i-PrONa, show extra hydrodechlorinating activity for di-chlorinated biphenyls.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Wu W,Xu J,Zhao H,Zhang Q,Liao S

doi

10.1016/j.chemosphere.2004.11.079

subject

Has Abstract

pub_date

2005-08-01 00:00:00

pages

944-50

issue

7

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(04)01164-6

journal_volume

60

pub_type

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