Abstract:
:In situ measurements of air and water phases at a wastewater treatment plant (WWTP) were used to investigate the partitioning behavior of perfluorocarboxylic acids (PFCAs), perfluorosulfonic acids (PFSAs) and perfluorooctyl sulfonamide (HFOSA) and their conjugate bases (PFC(-)s, PFS(-)s, and FOSA(-), respectively). Particle-dissolved (Rd) and air-water (QAW) concentration ratios were determined at different tanks of a WWTP. Sum of concentrations of C4-12,14 PFC(A)s, C4,6,8,10 PFS(A)s and (H)FOSA were as high as 50 pg m(-3) (atmospheric gas phase), 2300 ng L(-1) (aqueous dissolved phase) and 2500 ng L(-1) (aqueous particle phase). Particle-dissolved concentration ratios of total species, log Rd, ranged from -2.9 to 1.3 for PFS(A)s, from -1.9 to 1.1 for PFC(A)s and was 0.71 for (H)FOSA. These field-based values agree well with equilibrium partitioning data reported in the literature, suggesting that any in situ generation from precursors, if they are present in this system, occurs at a slower rate than the rate of approach to equilibrium. Acid QAW were also estimated. Good agreement between the QAW and the air-water equilibrium partition coefficient for C8PFCA suggests that the air above the WWTP tanks is at or near equilibrium with the water. Uncertainties in these QAW values are attributed mainly to variability in pKa values reported in the literature. The WWTP provides a unique environment for investigating environmental fate processes of the PFCAs and PFSAs under 'real' conditions in order to better understand and predict their fate in the environment.
journal_name
Chemospherejournal_title
Chemosphereauthors
Vierke L,Ahrens L,Shoeib M,Palm WU,Webster EM,Ellis DA,Ebinghaus R,Harner Tdoi
10.1016/j.chemosphere.2013.02.067subject
Has Abstractpub_date
2013-08-01 00:00:00pages
941-8issue
8eissn
0045-6535issn
1879-1298pii
S0045-6535(13)00379-2journal_volume
92pub_type
杂志文章相关文献
CHEMOSPHERE文献大全abstract::The stability of historically polycyclic aromatic hydrocarbon (PAH)-contaminated soils during cold storage was investigated. Samples from two former manufactured gas plants exhibited quantitative recoveries of PAHs over the whole period of sample holding at 4 degrees C in the dark (8-10 months), whereas significant lo...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(02)00497-6
更新日期:2002-12-01 00:00:00
abstract::Arbuscular mycorrhizal fungi (AMF) can form a symbiotic relationship with most terrestrial plant roots, promote plant growth, and heavy metal (HM) tolerance and thus plays a crucial role in phytoremediation. However, research on the relationship between colonization level and HM tolerance is limited. In this study, ap...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.129407
更新日期:2020-12-22 00:00:00
abstract::In this study, we used a 1H NMR based metabolomics strategy combined with gene expression analysis to determine the combined effects of gestational exposure of mice to BPA (10 μg/kg body weight by subcutaneous injection) and arsenic (10 ppb sodium arsenite in drinking water). Results showed that exposure to either BPA...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.07.094
更新日期:2018-11-01 00:00:00
abstract::Field monitoring was practiced from 2001 to 2003 to evaluate the input (irrigation, atmospheric deposition, and fertilizer application) and the output (uptake and accumulation into the above-ground biomass of rice plants and leaching) of cadmium (Cd) in a contaminated paddy field in Tokyo. The cadmium concentrations o...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2006.11.018
更新日期:2007-03-01 00:00:00
abstract::The content and type of polycyclic aromatic hydrocarbons (PAH) in soils from paddy fields and upland areas in South Korea were determined using gas chromatography linked to mass spectrometry (GC-MS). The distribution map of total PAH content was obtained as a contour plot using a geographical information system. The o...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(02)00764-6
更新日期:2003-03-01 00:00:00
abstract::Both pilot and laboratory scale experiments are conducted to compare the effect of ozone and permanganate preoxidation on algae removal by alum coagulation. Both appropriately dosed preoxidants are shown to be beneficial to algae coagulation removal. This may be attributed to a decrease in cell stability; however, ove...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2008.10.009
更新日期:2009-02-01 00:00:00
abstract::For many species, social learning is crucial for fitness-related activities, but human-induced environmental changes can impair such learning processes. For instance, mining can release the element, selenium (Se), that is vital for physiological functions but also has toxicological properties at elevated concentration...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.125898
更新日期:2020-05-01 00:00:00
abstract::The removal of pharmaceuticals present in wastewater is receiving more and more attention since most of them are refractory to traditional biological treatments. Many advanced oxidation processes have been reported in literature. However, cost estimations are not available for most of them. Recently, more environment ...
journal_title:Chemosphere
pub_type: 杂志文章,评审
doi:10.1016/j.chemosphere.2018.07.170
更新日期:2018-11-01 00:00:00
abstract::In this study, the structural alteration to DOC for a range of ultrasound treatments was investigated with chemical fractionation and UV-vis spectroscopic measurement. Ultrasound treatments were applied in continuous and pulsed modes at power levels of 48 and 84 W for effective treatment times of 5 and 15 min. Overall...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2015.11.079
更新日期:2016-02-01 00:00:00
abstract::Norfloxacin is a synthetic antibiotics drug which is widely used in the treatment of infectious diseases and also often carelessly released into natural environment resulting in antibiotics-contaminated wastewater. In this work, we employed atmospheric-pressure non-thermal dielectric barrier discharge (DBD) to treat n...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.07.035
更新日期:2018-11-01 00:00:00
abstract::The open reading frames of 19 cytochrome P450 monooxygenase (CYP) genes were sequenced from Chironomus tentans, a commonly used freshwater invertebrate model. Phylogenetic analysis of the 19 CYPs along with a previously reported CYP (CtCYP4G33) revealed that they belong to three different clans, including 3 in CYP4, 1...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.07.137
更新日期:2017-11-01 00:00:00
abstract::A simple method to functionalize diatomite with hydrous iron oxide was attempted and its performance as a new active filtration material to remove and recover phosphate from water was investigated under varying solution conditions. The Langmuir phosphate adsorption capacity increased from 0.6 mgP/g for raw diatomite t...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2015.10.015
更新日期:2016-02-01 00:00:00
abstract::The concentration of 9 polychlorinated biphenyls (PCB 28, 52, 101, 151, 153, 170, 180, 183 and 194) and of 6 micropollutants commonly classified as organochlorine pesticides, or OCPs (alpha-HCH, beta-HCH, gamma-HCH, p,p'-DDT, p,p'-DDE and p,p'-DDD), was determined in 22 sediment samples of lake Simbirizzi, an artifici...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(97)10035-2
更新日期:1998-03-01 00:00:00
abstract::Arsenic (As)-polluted groundwater constitutes a serious problem for peanut plants, as roots can accumulate the metalloid in their edible parts. Characterization of stress responses to As may help to detect potential risks and identify mechanisms of tolerance, being the induction of oxidative stress a key feature. Fift...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.04.104
更新日期:2017-08-01 00:00:00
abstract::The Stockholm Convention on Persistent Organic Pollutants (POPs) has established a global monitoring plan (GMP) to generate comparable data on the presence of POPs listed in the Stockholm Convention to identify changes in POPs concentrations over time and in regions. Perfluoroalkyl substances (PFAS) have been listed i...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2021.129612
更新日期:2021-01-13 00:00:00
abstract::In this work, we develop a model able to predict the equilibrium separation of gases due to differences in their molecular weights and the action of gravity. The separation of H, He, O, and N2 with altitude is a characteristic phenomenon of the heterosphere. The model is able to qualitatively recreate the compositiona...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.05.244
更新日期:2019-10-01 00:00:00
abstract::In a historical mining area residual material has been filled on land and these locations are used today as agricultural soils or house gardens. The antimony concentrations in these soils are up to 500 mg/kg. Antimony transfer into 19 vegetable and crop species was investigated. In grain and other storage organs up to...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(00)00037-0
更新日期:2000-12-01 00:00:00
abstract::In several countries such as the Netherlands, consumption of eel from polluted waters is not allowed because the concentrations of polychlorinated biphenyls (PCBs) exceed official tolerance limits. Few experiments have been carried out to assess if pre-treatment, such as cooking and frying would alter the PCB concentr...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2012.07.042
更新日期:2013-01-01 00:00:00
abstract::Measurements of airbone radionuclides (7)Be and gross beta (Aβ) jointly with atmospheric aerosols, i.e. particulate matter (PM) were routinely carried out for 10 years (2004-2014) at the University of the Balearic Islands, Spain. A total of 728 filter (0.8 μm pore size) samples were collected, and in all of them (7)Be...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.03.021
更新日期:2016-06-01 00:00:00
abstract::Polycyclic aromatic hydrocarbons (PAHs) are well known contaminants, ubiquitously present in the habitat and spawning areas for Atlantic cod (Gadus morhua). The Atlantic cod is a key species and a globally important food source, thus continuous monitoring of PAHs is considered highly valuable to ensure ecosystem susta...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.02.091
更新日期:2018-06-01 00:00:00
abstract::A workshop was held in Berlin September 12-14th 2012 to assess the state of the science of the data supporting low dose effects and non-monotonic dose responses ("low dose hypothesis") for chemicals with endocrine activity (endocrine disrupting chemicals or EDCs). This workshop consisted of lectures to present the cur...
journal_title:Chemosphere
pub_type: 社论
doi:10.1016/j.chemosphere.2013.06.043
更新日期:2013-10-01 00:00:00
abstract::Graphene is a promising material with a wide range of future applications that could potentially lead to its transfer from numerous water and terrestrial sources to the sea, thus fate and effects of graphene in the marine ecosystem deserve attention. Within this work, the impact of the short- and long-term exposure (3...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.128685
更新日期:2020-10-22 00:00:00
abstract::The European reference soil set was introduced as common basis for a better comparability of soil sorption data measured within the framework of chemical testing of environmental chemicals. The success of the EUROSOILS, as the set is commonly called, convinced the European Commission's Joint Research Centre to evaluat...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(00)00015-1
更新日期:2000-11-01 00:00:00
abstract::Mercury (Hg) is known as a highly toxic heavy metal, and its toxicity varies depending on its form due to different toxicokinetics between inorganic and organic Hg. Limited information on comparison of Hg toxicity concerning its chemical form by oral exposure is currently available in cultured fishes. Therefore, we co...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.127611
更新日期:2020-12-01 00:00:00
abstract::Eleven species of Neotropical migrant passerines collected in Illinois (USA) during May 1996, were analyzed for the presence of organochlorine (OC) pesticides. At least one of five OC pesticide residues was detected in 66 of 72 birds, representing all species examined. The contaminants most frequently detected were p,...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(99)00561-5
更新日期:2000-10-01 00:00:00
abstract::In the present study, we investigated the effect of different carbon sources (glucose, glycerol and ground mandarin peelings) on laccase production by Trametes pubescens grown on stainless steel sponges under static conditions. The cultures with ground mandarin peelings gave the highest laccase activities, showing val...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2006.11.051
更新日期:2007-04-01 00:00:00
abstract::The tissue distribution, bioconcentration, metabolism and biological effects of the antifungal medication ketoconazole were investigated in fish, crucian carp (Carassius auratus) were exposed to a series of nominal concentrations (0.2, 2 and 20 μg/L) for 14 days. The ultra-high performance liquid chromatography tandem...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.02.033
更新日期:2016-05-01 00:00:00
abstract::The aquatic fate and persistence of synthetic pyrethroids under spray drift and field runoff treatment regimens were determined in outdoor pond microcosms. In this paper, the experimental design and construction of outdoor microcosms is presented, as well as the aquatic fate of tralomethrin and deltamethrin. Tralometh...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(99)00064-8
更新日期:1999-10-01 00:00:00
abstract::Dust is a mixture of natural and anthropogenic particles originated from multiple sources, which can represent an hazard for human health. Playgrounds are a site of particularly concern, due to sand dust ingestion by toddlers and inhalation. In this study, 37 sands used in public playgrounds in the city of Barcelona w...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.09.101
更新日期:2018-01-01 00:00:00
abstract::In this study, a facile and effective route to prepare hybrid photocatalysts (paper-TiO2, paper-TiO2-AgBr and paper-AgBr-TiO2) has been reported. The preparation procedure consisted of the direct adsorption of the previously synthesized titania nanoparticles (TiO2 sol) to generate the TiO2 nanosphere and the immersion...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.128703
更新日期:2020-10-22 00:00:00