Abstract:
:The present study reports pyrolysis behavior of three waste biomass using thermogravimetric analysis to determine kinetic parameters at five different heating rates. Physiochemical characterization confirmed that these biomass have the potential for fuel and energy production. Pyrolysis experiments were carried out at five different heating rates (5-25 °C min-1). Five model-free methods such as Kissinger-Akahira-Sunose (KAS), Ozawa-Flynn-Wall (OFW), Friedman, Coats-Redfern, and distributed activation energy (DAEM) were used to calculate the kinetic parameters. The activation energy was found to be 171.66 kJ mol-1, 148.44 kJ mol-1, and 171.24 kJ mol-1 from KAS model; 179.29 kJ mol-1, 156.58 kJ mol-1, and 179.47 kJ mol-1 from OFW model; 168.58 kJ mol-1, 181.53 kJ mol-1, and 184.61 kJ mol-1 from Friedman model; and 206.62 kJ mol-1, 171.63 kJ mol-1, and 160.45 kJ mol-1 from DAEM model for PW, SW, AN biomass respectively. The calculated kinetic parameters are in good agreement with other reported biomass.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Mishra RK,Mohanty Kdoi
10.1016/j.biortech.2017.12.029subject
Has Abstractpub_date
2018-03-01 00:00:00pages
63-74eissn
0960-8524issn
1873-2976pii
S0960-8524(17)32162-4journal_volume
251pub_type
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