Abstract:
:Quantitative recovery is necessary for scale-up application of acidic ionic liquids (AILs). Ultrafiltration and bipolar membrane electrodialysis (BMED) was employed for the recovery and regeneration of acidic ionic liquid 1-butyl-3-methylimidazolium hydrogen sulphate (Bmim[HSO4]) after biomass pretreatment. Ultrafiltration was designed for the purification of BMED feed solution. During BMED treatment, Bmim+ retention with OH- generation occurred in mixing section and SO42- immigration with H+ generation occurred in aciding section. Resulting aqueous Bmim[OH] in mixing section and H2SO4 in aciding section could be utilized for quantitative synthesis of Bmim[HSO4]. Influence of BMED operating mode and major parameters including BMED feed concentration and current density of BMED module were studied in detail. The highest recovery ratio for Bmim+ and SO42- reached 96.2% and 96.0%. And the lowest energy consumption of specific Bmim[HSO4] recovery approached 9.0 kw∙h/kg. Insight gained from this study suggested a sustainable biomass processing methodology using AILs.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Liang X,Wang J,Liu Hdoi
10.1016/j.biortech.2021.124726subject
Has Abstractpub_date
2021-01-18 00:00:00pages
124726eissn
0960-8524issn
1873-2976pii
S0960-8524(21)00065-1journal_volume
325pub_type
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