Catalytic valorization of starch-rich food waste into hydroxymethylfurfural (HMF): Controlling relative kinetics for high productivity.

Abstract:

:This study aimed to maximize the valorization of bread waste, a typical food waste stream, into hydroxymethylfurfural (HMF) by improving our kinetic understanding. The highest HMF yield (30mol%) was achieved using SnCl4 as catalyst, which offered strong derived Brønsted acidity and moderate Lewis acidity. We evaluated the kinetic balance between these acidities to facilitate faster desirable reactions (i.e., hydrolysis, isomerization, and dehydration) relative to undesirable reactions (i.e., rehydration and polymerization). Such catalyst selectivity of SnCl4, AlCl3, and FeCl3 was critical in maximizing HMF yield. Higher temperature made marginal advancement by accelerating the undesirable reactions to a similar extent as the desirable pathways. The polymerization-induced metal-impregnated high-porosity carbon was a possible precursor of biochar-based catalyst, further driving up the economic potential. Preliminary economic analysis indicated a net gain of USD 43-236 per kilogram bread waste considering the thermochemical-conversion cost and chemical-trading revenue.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Yu IKM,Tsang DCW,Yip ACK,Chen SS,Wang L,Ok YS,Poon CS

doi

10.1016/j.biortech.2017.01.017

subject

Has Abstract

pub_date

2017-08-01 00:00:00

pages

222-230

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(17)30037-8

journal_volume

237

pub_type

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