Assessment of indoor HONO formation mechanisms based on in situ measurements and modeling.

Abstract:

:The photolysis of HONO has been found to be the oxidation driver through OH formation in the indoor air measurement campaign SURFin, an extensive campaign carried out in July 2012 in a classroom in Marseille. In this study, the INCA-Indoor model is used to evaluate different HONO formation mechanisms that have been used previously in indoor air quality models. In order to avoid biases in the results due to the uncertainty in rate constants, those parameters were adjusted to fit one representative day of the SURFin campaign. Then, the mechanisms have been tested with the optimized parameters against other experiments carried out during the SURFin campaign. Based on the observations and these findings, we propose a new mechanism incorporating sorption of NO2 onto surfaces with possible saturation of these surfaces. This mechanism is able to better reproduce the experimental profiles over a large range of conditions.

journal_name

Indoor Air

journal_title

Indoor air

authors

Mendez M,Blond N,Amedro D,Hauglustaine DA,Blondeau P,Afif C,Fittschen C,Schoemaecker C

doi

10.1111/ina.12320

subject

Has Abstract

pub_date

2017-03-01 00:00:00

pages

443-451

issue

2

eissn

0905-6947

issn

1600-0668

journal_volume

27

pub_type

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