Abstract:
:The photolysis of HONO has been found to be the oxidation driver through OH formation in the indoor air measurement campaign SURFin, an extensive campaign carried out in July 2012 in a classroom in Marseille. In this study, the INCA-Indoor model is used to evaluate different HONO formation mechanisms that have been used previously in indoor air quality models. In order to avoid biases in the results due to the uncertainty in rate constants, those parameters were adjusted to fit one representative day of the SURFin campaign. Then, the mechanisms have been tested with the optimized parameters against other experiments carried out during the SURFin campaign. Based on the observations and these findings, we propose a new mechanism incorporating sorption of NO2 onto surfaces with possible saturation of these surfaces. This mechanism is able to better reproduce the experimental profiles over a large range of conditions.
journal_name
Indoor Airjournal_title
Indoor airauthors
Mendez M,Blond N,Amedro D,Hauglustaine DA,Blondeau P,Afif C,Fittschen C,Schoemaecker Cdoi
10.1111/ina.12320subject
Has Abstractpub_date
2017-03-01 00:00:00pages
443-451issue
2eissn
0905-6947issn
1600-0668journal_volume
27pub_type
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