Sub-supercritical liquefaction of rice stalk for the production of bio-oil: Effect of solvents.

Abstract:

:The effect of solvents (water and ethanol) on liquefaction characteristics of rice stalk (RS) was investigated in an autoclave. The highest conversion and liquid yield in water and ethanol were 84.95 wt%, 72.62 wt% and 78.93wt%, 63.84 wt%, respectively. FTIR and GC-MS of the bio-oils obtained from subcritical water (SubH2O, 300°C) and supercritical ethanol (scEtOH, 300°C) indicated that the behavior of RS liquefaction depended on solvents used. The major components of bio-oil produced in SubH2O were ketones and phenols, while esters and phenols dominated in scEtOH. ICP-OES analysis showed that the concentrations of potassium (K) and sodium (Na) in the bio-oil obtained from scEtOH were 14-15 times higher than that obtained from SubH2O. Ethanol gave rise to an improvement in the bio-oil properties including water content, density, acidity and HHV. It was concluded that the bio-oil from RS can be effectively upgraded in scEtOH.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Li R,Li B,Yang T,Kai X,Wang W,Jie Y,Zhang Y,Chen G

doi

10.1016/j.biortech.2015.08.088

subject

Has Abstract

pub_date

2015-12-01 00:00:00

pages

94-100

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(15)01194-3

journal_volume

198

pub_type

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