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Vanadium-catalyzed chlorination under molecular oxygen.

Abstract：

:A catalytic chlorination of ketones was performed by using a vanadium catalyst in the presence of Bu4NI and AlCl3 under atmospheric molecular oxygen. This catalytic chlorination could be applied to the chlorination of alkenes to give the corresponding vic-dichlorides. AlCl3 was found to serve as both a Lewis acid and a chloride source to induce the facile chlorination. A combination of Bu4NI and AlI3 in the presence of a vanadium catalyst under atmospheric molecular oxygen induced the iodination of ketones.

journal_name

J Inorg Biochem

journal_title

Journal of inorganic biochemistry

authors

Moriuchi T,Fukui Y,Kato S,Kajikawa T,Hirao T

doi

10.1016/j.jinorgbio.2015.01.015

subject

Has Abstract

pub_date

2015-06-01 00:00:00

pages

177-80

eissn

0162-0134

issn

1873-3344

pii

S0162-0134(15)00032-X

journal_volume

147

pub_type

杂志文章

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