Abstract:
:Aqueous solubilities of four non-ortho and eight mono-ortho substituted PCBs were determined using a generator-column technique followed by subsequent off-line GC/ECD analysis of the aqueous solutions. The method is based on pumping water through a column containing glass beads coated with the congener being studied and has been used to measure solubilities at room temperature. The method circumvents many of the experimental difficulties encountered with the traditional shake-flask system. Aqueous solubility of 3,3',4,4'-tetrachlorobiphenyl determined by this procedure is compared with data obtained from the shake-flask method and the computational method. The precision of replicate measurements is better than +/- 6.5%. Aqueous solubilities determined for 12 congeners ranged from 6.07 x 10(-11) to 4.47 x 10(-9) mol/L and generally decreased with molecular weight and increased with degree of ortho-chlorine substitution within a molecular-weight class.
journal_name
Chemospherejournal_title
Chemosphereauthors
Hong CS,Qiao Hdoi
10.1016/0045-6535(95)00313-wsubject
Has Abstractpub_date
1995-12-01 00:00:00pages
4549-57issue
11-12eissn
0045-6535issn
1879-1298pii
0045-6535(95)00313-Wjournal_volume
31pub_type
杂志文章相关文献
CHEMOSPHERE文献大全abstract::The influences of total organic carbon (TOC) and total nitrogen (TN) on Lead-210 (210Pb) dating have recently been of increasing concern in lacustrine research. Sediment core from Changshou Lake in the Longxi catchment was investigated for influence of TOC on 210Pb dating. Lead-210 excess (210Pbex), Cesium-137 (137Cs)...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.01.060
更新日期:2017-05-01 00:00:00
abstract::An advanced oxidation treatment, UV/H2O2, was applied to an azo dye, Hispamin Black CA, widely used in the Peruvian textile industry. Rates of color removal and degradation of the dye have been evaluated. A strongly absorbing solution was completely decolorized after 35 min of treatment, and after 60 min an 82% reduct...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(02)00117-0
更新日期:2002-07-01 00:00:00
abstract::Biosorption of heavy metals by bacterial biomass has been the subject of significant research interest in last decades due to its efficiency, relatively low cost and minimal negative effects for the surrounding environment. In this meta-analysis, the biosorption efficiencies of different bacterial strains for Cu(II), ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.129290
更新日期:2020-12-11 00:00:00
abstract::Cadmium chloride (Cd) is a potent endocrine disruptor and may cause the malformation in the male reproductive tract. However, the effects of a single in utero exposure to low doses of Cd on fetal Leydig cell development are still unknown. The objective of this study is to investigate the effects of a single in utero e...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.11.159
更新日期:2018-03-01 00:00:00
abstract::Acid rain is a problem of increasing agricultural, environmental, and ecological concerns worldwide. This study investigated impacts of simulated acid rain (SAR) on cation leaching from the Latosol in south China. Latosol is an acidic red soil and occurs in the tropical rainforest biome. Laboratory experiments were pe...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2006.12.095
更新日期:2007-05-01 00:00:00
abstract::The oribatid mite, Oppia nitens, has gained recognition in recent laboratory ecotoxicological tests, however, the species global distribution is limited to temperate regions and not ecologically relevant for tropical soils. The present study reports the first laboratory study aimed at assessing the ecotoxicity of cont...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.11.173
更新日期:2019-03-01 00:00:00
abstract::A toxicity test was developed to examine the effects of heavy metal contaminants on the early life stages of the marine polychaete. We have studied the effects of metals on fertilization and early development of marine polychaete Hydroides elegans. These heavy metals have often been found in polluted ground and water ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2007.09.062
更新日期:2008-03-01 00:00:00
abstract::The aerobic visible-light-photosensitised irradiation of methanolic solutions of either of the phenolic-type contaminants model compounds (ArOH) p-phenylphenol (PP), p-nitrophenol (NP) and phenol (Ph), and for two additional phenolic derivatives, namely p-chlorophenol (ClP) and p-methoxyphenol (MeOP), used in some exp...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2004.01.016
更新日期:2004-06-01 00:00:00
abstract::The aryl hydrocarbon receptor (AhR) plays a key role in the regulation of gene expression in metabolic machinery and detoxification systems. In the recent years, this receptor has attracted interest as a therapeutic target for immunological, oncogenic and inflammatory conditions. In the present report, in silico and i...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.127068
更新日期:2020-10-01 00:00:00
abstract::Chelant assisted phytoextraction has been proposed to enhance the efficiency of remediation. This study evaluated the effects of biodegradable ethylene diamine tetraacetate (EDDS), nitrilotriacetic (NTA) and anionic polyacrylamide (APAM) on the tolerance and uptake of Siegesbeckia orientalis L. at 10 and 100 mg kg(-1)...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2013.01.116
更新日期:2013-05-01 00:00:00
abstract::Sorption onto clays (montmorillonite and kaolinite), oxidation and sorption by manganese oxides (synthesized MnO and natural MnO), and coupled sorption-oxidation experiments were conducted for the removal of antibiotics sulfadiazine (SDZ) and ciprofloxacin (CIP) at pH 5 and 8. Individual sorption and oxidation modelli...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.126251
更新日期:2020-07-01 00:00:00
abstract::The occurrence of oocytes in the testis (testis-ova) of several fish species is often associated with exposure of estrogenic chemicals. However, induction mechanisms of the testis-ova remain to be elucidated. To develop marker genes for detecting testis-ova in the testis, adult male medaka were exposed to nominal conc...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2011.12.047
更新日期:2012-05-01 00:00:00
abstract::Chemosensors have attracted increasing attention for their usefulness on-site detection and monitoring. In this study, we elucidated a novel, facile, and highly selective Chemo-Paper-Sensor (CPS) for detection and monitoring of strontium (Sr(2+)) ions, which means a potent colorimetric sensor based on a Chrysoidine G ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.02.110
更新日期:2016-06-01 00:00:00
abstract::Carbon isotope fractionation was observed during dechlorination of 1,2,3,4-tetrachlorodibenzo-p-dioxin (1,2,3,4-TeCDD) by a mixed culture containing Dehalococcoides ethenogenes strain 195. Fractionation was examined when 1,2,3,4-TeCDD was added as the only chlorinated compound and when 1,2,3,4-TeCDD was added with a k...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2010.06.027
更新日期:2010-08-01 00:00:00
abstract::A fine porcelain open-cell photo-catalytic filter with titanium dioxide (TiO(2)) was evaluated for sterilization and sanitation of bio-polluted industrial water. In simulated seawater industrial effluent samples, the populations of Escherichia coli and Vibrio parahaemolyticus quickly decreased and reached non-detectab...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2005.03.061
更新日期:2006-01-01 00:00:00
abstract::Atrazine is well known to be a biologically hazardous substance with toxic effects, but atrazine-induced neurotoxicity remains unclear. The aim of this study was to investigate the mechanisms of atrazine-induced cerebellar toxicity. To determine atrazine-exerted potential neurotoxicity, quails were treated with 50, 25...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.12.075
更新日期:2017-03-01 00:00:00
abstract::We examined the secondary production of halogenated derivatives of polycyclic aromatic hydrocarbons (PAHs) in surface seawater. Pyrene was selected as the model compound and exposed to UV irradiation in synthetic seawater for various irradiation times. Pyrene underwent rapid photochemical reactions that produced vario...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.12.044
更新日期:2017-03-01 00:00:00
abstract::The effect of the pesticide glyphosate (GPS) on adsorption processes of copper onto three soils of different characteristics has been studied. Cu adsorption decreases in general with increasing GPS concentration in solution, due principally to the lower equilibrium pHs, although this is not the only variable affecting...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(01)00338-1
更新日期:2002-05-01 00:00:00
abstract::Fish is among the essential components of Mediterranean diet and has beneficial effects on human health. Farmed fish is an affordable alternative to wild fish and a significant food export product for Greece. Published studies worldwide have reported significant levels of environmental pollutants in fish tissues. Espe...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2015.12.019
更新日期:2016-03-01 00:00:00
abstract::During present investigations, renal toxicity of CdSNPs (cadmium sulphide nanoparticles) (ranged 5-9 nm) was estimated in rat employing specific parameters. Treatment on each alternate day for 45 days with CdSNPs (10 mg/kg b.w.) yielded significant increase in Cd-MT (cadmium metallothionein), lipid peroxidation and H2...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.11.011
更新日期:2018-02-01 00:00:00
abstract::Semi-domesticated reindeer and wild moose meat samples were analyzed for polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), and polychlorinated biphenyls (PCBs). Both calves and adults were studied. Individual reindeer and moose meat samples and pooled reindeer calf meat samples were collected from the nor...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2009.01.013
更新日期:2009-05-01 00:00:00
abstract::Twenty-four surficial sediment samples, representing different environments within the Venice Lagoon, were analyzed for polychlorinated biphenyls (PCBs) in order to assess degrees of pollution, sources, areal distribution, and potential risk for the environment. Concentrations in surficial sediments range from 2 to mo...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(00)00408-2
更新日期:2001-05-01 00:00:00
abstract::Aquatic humic substance (AHS) in landfill leachate is resistant to biodegradation, especially in anaerobic habitats. However, we reported here for the first time that AHS was completely biodegraded with the anaerobic ammonium oxidation (Anammox) process. As a result of aromatic-ring cleavage and mineralization, carbox...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2008.11.073
更新日期:2009-03-01 00:00:00
abstract::Ononitol monohydrate isolated from the ethyl acetate extract of Cassia tora L. using column chromatography was evaluated for its antifeedant, larvicidal and growth inhibitory activities against Helicoverpa armigera and Spodoptera litura at different concentrations of 125, 250, 500 and 1000 ppm. Leaf disc no-choice met...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2012.02.051
更新日期:2012-07-01 00:00:00
abstract::Microbial remediation of heavy metal-polluted soil is a commonly used method. Burkholderia sp. Y4, isolated from cadmium (Cd)-contaminated rice rhizosphere soil, was investigated for its direct and indirect effects on Cd accumulation in rice by SEM-EDS, FITR and sequencing analysis of the soil bacterial community. Bur...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.126603
更新日期:2020-08-01 00:00:00
abstract::While large quantities of studies on microplastics in the marine environment have been widely carried out, few were available in the freshwater environment. The occurrence and characteristics, including composition, abundance, surface texture and interaction with heavy metals, of microplastics in the surface sediments...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.12.074
更新日期:2017-03-01 00:00:00
abstract::Enhanced Biological Phosphorus Removal (EBPR) of urban wastewaters is usually limited by the available carbon source required by Polyphosphate Accumulating Organisms (PAO). External carbon sources as volatile fatty acids (VFA) or other pure organic compounds have been tested at lab scale demonstrating its ability to e...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2015.05.067
更新日期:2015-12-01 00:00:00
abstract::Sorption of 17alpha-ethinyl estradiol (EE2) and bisphenol A (BPA) by nonhydrolyzable carbon (NHC), black carbon (BC), and bulk soils and sediments was examined. All sorption isotherms were nonlinear and fitted both Freundlich and Dubinin-Ashtakhov (DA) models. The single-point organic carbon (OC)-normalized distributi...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2010.05.028
更新日期:2010-08-01 00:00:00
abstract::A method for the determination of dioxins, planar PCBs and other PCBs in human milk is described. The work is part of a big Dutch project, (seven institutes participates) in which 400 human milk samples from two areas (Rotterdam and Groningen) taken at two different times (10 and 42 days) after delivery had to be anal...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/0045-6535(94)90352-2
更新日期:1994-11-01 00:00:00
abstract::In the present paper, inorganic arsenic species and chemical parameters in groundwater were determined to investigate the factors related to the distribution of arsenic species and their dissolution from rock into groundwater. For the study, groundwater and core samples were taken at different depths of two newly dril...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/S0045-6535(03)00244-3
更新日期:2003-07-01 00:00:00