Real time monitoring of a biogas digester with gas chromatography, near-infrared spectroscopy, and membrane-inlet mass spectrometry.

Abstract:

:Four methods of monitoring the anaerobic digestion process were studied at pilot scale. The methods employed were Micro Gas Chromatography (μ-GC) and Membrane Inlet Mass Spectrometry (MIMS) for measurements in the gas phase, Near Infrared Spectroscopy (NIRS) and pH in the liquid phase. Micro Gas Chromatography accurately measured H(2), CH(4), H(2)S, N(2) and O(2) in the headspace whereas the MIMS accurately measured CH(4), CO(2), H(2)S, reduced organic sulfur compounds and p-cresol, also in the headspace. In the liquid phase, NIRS was found to be suitable for estimating the concentrations of acetate, propionate and total volatile fatty acids (VFA) but the error of prediction was too large for accurate quantification. Both the μ-GC and NIRS were low maintenance methods whereas the MIMS required frequent cleaning and background measurements.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Ward AJ,Bruni E,Lykkegaard MK,Feilberg A,Adamsen AP,Jensen AP,Poulsen AK

doi

10.1016/j.biortech.2010.12.052

subject

Has Abstract

pub_date

2011-03-01 00:00:00

pages

4098-103

issue

5

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(10)02015-8

journal_volume

102

pub_type

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