Particle concentration effect: adsorption of divalent metal ions on coffee grounds.

Abstract:

:The adsorption of divalent metal ions Cu2+, Pb2+, Zn2+, and Cd2+ on coffee grounds as a function of coffee grounds concentration was studied in which adsorption density decreased as the concentration of coffee grounds (C(s)) increased. Adsorption studies were conducted by equilibrating aqueous solutions of each metal ion at concentrations in the range 19-291 micromol L(-1) with coffee suspensions in the concentration range 0.971-8.738 g L(-1), with the initial pH adjusted to 5.0+/-0.1 using NaOH or HNO3. Metastable Equilibrium Adsorption theory did not adequately explain the adsorption phenomenon, except at low concentrations of coffee grounds and trace metal ions. Instead the results indicated that flocculation might reduce the surface availability thus reducing the adsorption density. The flocculation theory was confirmed after a further experiment adding dispersant sodium hexa-meta-phosphate (NaHMP) to the suspension.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Utomo HD,Hunter KA

doi

10.1016/j.biortech.2009.06.094

subject

Has Abstract

pub_date

2010-03-01 00:00:00

pages

1482-6

issue

5

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(09)00779-2

journal_volume

101

pub_type

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