Abstract:
:Azo dyes are of synthetic origin and their environmental fate is not well understood. They are resistant to direct aerobic bacterial degradation and form potentially carcinogenic aromatic amines by reduction of the azo group. This study shows that applying the oxidative processes of enzymatic treatment with laccase and ultrasound treatment, both alone and in combination, leads to dye degradation. Laccase treatment degraded both Acid Orange and Direct Blue dyes within 1-5 h but failed in the case of Reactive dyes, whereas ultrasound degraded all the dyes investigated (3-15 h). When applied as multi-stage combinations the treatments showed synergistic effects for dye degradation compared with individual treatments. Bulk light absorption (UV-Vis) and ion pairing HPLC were used for process monitoring. Additionally, mass spectrometry was used to elucidate the structures of intermediates arising from ultrasound treatment.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Tauber MM,Gübitz GM,Rehorek Adoi
10.1016/j.biortech.2007.08.085subject
Has Abstractpub_date
2008-07-01 00:00:00pages
4213-20issue
10eissn
0960-8524issn
1873-2976pii
S0960-8524(07)00704-3journal_volume
99pub_type
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