Degradation of azo dyes by oxidative processes--laccase and ultrasound treatment.

Abstract:

:Azo dyes are of synthetic origin and their environmental fate is not well understood. They are resistant to direct aerobic bacterial degradation and form potentially carcinogenic aromatic amines by reduction of the azo group. This study shows that applying the oxidative processes of enzymatic treatment with laccase and ultrasound treatment, both alone and in combination, leads to dye degradation. Laccase treatment degraded both Acid Orange and Direct Blue dyes within 1-5 h but failed in the case of Reactive dyes, whereas ultrasound degraded all the dyes investigated (3-15 h). When applied as multi-stage combinations the treatments showed synergistic effects for dye degradation compared with individual treatments. Bulk light absorption (UV-Vis) and ion pairing HPLC were used for process monitoring. Additionally, mass spectrometry was used to elucidate the structures of intermediates arising from ultrasound treatment.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Tauber MM,Gübitz GM,Rehorek A

doi

10.1016/j.biortech.2007.08.085

subject

Has Abstract

pub_date

2008-07-01 00:00:00

pages

4213-20

issue

10

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(07)00704-3

journal_volume

99

pub_type

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