Bioleaching of spent fluid catalytic cracking catalyst using Aspergillus niger.

Abstract:

:The use of the fungus Aspergillus niger for the bioleaching of heavy metals from spent catalyst was investigated, with fluid catalytic cracking (FCC) catalyst as a model. Bioleaching was examined in batch cultures with the spent catalysts at various pulp densities (1-12%). Chemical leaching was also performed using mineral acids (sulphuric and nitric acids) and organic acids (citric, oxalic and gluconic acids), as well as a mixture of organic acids at the same concentrations as that biogenically produced. It was shown that bioleaching realised higher metal extraction than chemical leaching, with A. niger mobilizing Ni (9%), Fe (23%), Al (30%), V (36%) and Sb (64%) at 1% pulp density. Extraction efficiency generally decreased with increased pulp density. Compared with abiotic controls, bioleaching gave rise to higher metal extractions than leaching using fresh medium and cell-free spent medium. pH decreased during bioleaching, but remained relatively constant in both leaching using fresh medium and cell-free spent medium, thus indicating that the fungus played a role in effecting metal extraction from the spent catalyst.

journal_name

J Biotechnol

journal_title

Journal of biotechnology

authors

Aung KM,Ting YP

doi

10.1016/j.jbiotec.2004.10.008

subject

Has Abstract

pub_date

2005-03-16 00:00:00

pages

159-70

issue

2

eissn

0168-1656

issn

1873-4863

pii

S0168-1656(04)00520-6

journal_volume

116

pub_type

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