Quantitative estimation of peat, brown coal and lignite humic acids using chemical parameters, 1H-NMR and DTA analyses.

Abstract:

:Humic acids extracted from peats (P), brown coals (BC) and lignites (L), were characterized using different (chemical, 1H-nuclear magnetic resonance spectroscopy and differential thermal analysis) techniques. Fourteen variables were obtained from these analyses and only five were selected because uncorrelated in multiple partial correlation. The chosen variables were C concentration, aliphatic and aromatic components and the heat of reaction of the second exothermic peak. The multivariate discriminant analysis was performed on these variables and a discriminant function was obtained which was able to efficiently separate the P, BC and L. This function enables simple predictions on samples of unknown origin. The straightforward method proposed and the results obtained are discussed.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Francioso O,Ciavatta C,Montecchio D,Tugnoli V,Sánchez-Cortés S,Gessa C

doi

10.1016/s0960-8524(03)00004-x

subject

Has Abstract

pub_date

2003-07-01 00:00:00

pages

189-95

issue

3

eissn

0960-8524

issn

1873-2976

pii

S096085240300004X

journal_volume

88

pub_type

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