Abstract:
:In this contribution, olefin block copolymers were produced via chain shuttling polymerization (CSP), using a new combination of catalysts and a chain shuttling agent (CSA) diethylzinc (ZnEt2). The binary catalyst system included nonbridged half-titanocene catalyst, Cp*TiCl2(O-2,6-iPr2C6H3) (Cat A) and bis(phenoxy-imine) zirconium, {η2-1-[C(H)=NC6H11]-2-O-3-tBu-C6H3}2ZrCl2 (Cat B), as well as co-catalyst methylaluminoxane (MAO). In contrast to dual-catalyst system in the absence of CSA, the blocky structure was obtained in the presence of CSA and rationalized from rheological studies. The binary catalyst system could cause the CSP reaction to occur in the presence of CSA ZnEt2, which yielded broad distribution ethylene/1-octene copolymers (Mw/Mn: 35.86) containing block polymer chains with high Mw. The presented dual-catalytic system was applied for the first time in CSP and has a potential to be extended to produce a library of olefin block copolymers that can be used as advanced additives for thermoplastics.
journal_name
R Soc Open Scijournal_title
Royal Society open scienceauthors
Xu Q,Gao R,Liu Ddoi
10.1098/rsos.182007subject
Has Abstractpub_date
2019-04-10 00:00:00pages
182007issue
4issn
2054-5703pii
rsos182007journal_volume
6pub_type
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