当前位置： SCI文献检索 > Nature Communications期刊下所有文献 > Understanding crystallization pathways leading to manganese oxide polymorph formation.

Understanding crystallization pathways leading to manganese oxide polymorph formation.

Abstract：

:Hydrothermal synthesis is challenging in metal oxide systems with diverse polymorphism, as reaction products are often sensitive to subtle variations in synthesis parameters. This sensitivity is rooted in the non-equilibrium nature of low-temperature crystallization, where competition between different metastable phases can lead to complex multistage crystallization pathways. Here, we propose an ab initio framework to predict how particle size and solution composition influence polymorph stability during nucleation and growth. We validate this framework using in situ X-ray scattering, by monitoring how the hydrothermal synthesis of MnO2 proceeds through different crystallization pathways under varying solution potassium ion concentrations ([K+] = 0, 0.2, and 0.33 M). We find that our computed size-dependent phase diagrams qualitatively capture which metastable polymorphs appear, the order of their appearance, and their relative lifetimes. Our combined computational and experimental approach offers a rational and systematic paradigm for the aqueous synthesis of target metal oxides.

journal_name

Nat Commun

journal_title

Nature communications

authors

Chen BR,Sun W,Kitchaev DA,Mangum JS,Thampy V,Garten LM,Ginley DS,Gorman BP,Stone KH,Ceder G,Toney MF,Schelhas LT

doi

10.1038/s41467-018-04917-y

subject

Has Abstract

pub_date

2018-06-29 00:00:00

pages

2553

issue

1

issn

2041-1723

pii

10.1038/s41467-018-04917-y

journal_volume

9

pub_type

杂志文章

相关文献

Nature Communications文献大全
  • Hydrodynamic phonon transport in suspended graphene.

    abstract：:Recent studies of thermal transport in nanomaterials have demonstrated the breakdown of Fourier's law through observations of ballistic transport. Despite its unique features, another instance of the breakdown of Fourier's law, hydrodynamic phonon transport, has drawn less attention because it has been observed only a...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms7290

    authors： Lee S,Broido D,Esfarjani K,Chen G

    更新日期：2015-02-18 00:00:00

  • Bipartite electronic superstructures in the vortex core of Bi2Sr2CaCu2O8+δ.

    abstract：:The central issue in the physics of cuprate superconductivity is the mutual relationship among superconductivity, pseudogap and broken-spatial-symmetry states. A magnetic field B suppresses superconductivity, providing an opportunity to investigate the competition among these states. Although various B-induced electro...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms11747

    authors： Machida T,Kohsaka Y,Matsuoka K,Iwaya K,Hanaguri T,Tamegai T

    更新日期：2016-05-27 00:00:00

  • Land-use emissions play a critical role in land-based mitigation for Paris climate targets.

    abstract：:Scenarios that limit global warming to below 2 °C by 2100 assume significant land-use change to support large-scale carbon dioxide (CO2) removal from the atmosphere by afforestation/reforestation, avoided deforestation, and Biomass Energy with Carbon Capture and Storage (BECCS). The more ambitious mitigation scenarios...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-05340-z

    authors： Harper AB,Powell T,Cox PM,House J,Huntingford C,Lenton TM,Sitch S,Burke E,Chadburn SE,Collins WJ,Comyn-Platt E,Daioglou V,Doelman JC,Hayman G,Robertson E,van Vuuren D,Wiltshire A,Webber CP,Bastos A,Boysen L,Ciais

    更新日期：2018-08-07 00:00:00

  • Coherent structural trapping through wave packet dispersion during photoinduced spin state switching.

    abstract：:The description of ultrafast nonadiabatic chemical dynamics during molecular photo-transformations remains challenging because electronic and nuclear configurations impact each other and cannot be treated independently. Here we gain experimental insights, beyond the Born-Oppenheimer approximation, into the light-induc...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms15342

    authors： Lemke HT,Kjær KS,Hartsock R,van Driel TB,Chollet M,Glownia JM,Song S,Zhu D,Pace E,Matar SF,Nielsen MM,Benfatto M,Gaffney KJ,Collet E,Cammarata M

    更新日期：2017-05-24 00:00:00

  • Efficient non-Markovian quantum dynamics using time-evolving matrix product operators.

    abstract：:In order to model realistic quantum devices it is necessary to simulate quantum systems strongly coupled to their environment. To date, most understanding of open quantum systems is restricted either to weak system-bath couplings or to special cases where specific numerical techniques become effective. Here we present...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-05617-3

    authors： Strathearn A,Kirton P,Kilda D,Keeling J,Lovett BW

    更新日期：2018-08-20 00:00:00

  • Mechanisms of drug interactions between translation-inhibiting antibiotics.

    abstract：:Antibiotics that interfere with translation, when combined, interact in diverse and difficult-to-predict ways. Here, we explain these interactions by "translation bottlenecks": points in the translation cycle where antibiotics block ribosomal progression. To elucidate the underlying mechanisms of drug interactions bet...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-17734-z

    authors： Kavčič B,Tkačik G,Bollenbach T

    更新日期：2020-08-11 00:00:00

  • Solderable and electroplatable flexible electronic circuit on a porous stretchable elastomer.

    abstract：:A variety of flexible and stretchable electronics have been reported for use in flexible electronic devices or biomedical applications. The practical and wider application of such flexible electronics has been limited because commercial electronic components are difficult to be directly integrated into flexible stretc...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms1980

    authors： Jeong GS,Baek DH,Jung HC,Song JH,Moon JH,Hong SW,Kim IY,Lee SH

    更新日期：2012-01-01 00:00:00

  • Layer-by-layer biofunctionalization of nanostructured porous silicon for high-sensitivity and high-selectivity label-free affinity biosensing.

    abstract：:Nanostructured materials premise to revolutionize the label-free biosensing of analytes for clinical applications, leveraging the deeper interaction between materials and analytes with comparable size. However, when the characteristic dimension of the materials reduces to the nanoscale, the surface functionalization f...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-07723-8

    authors： Mariani S,Robbiano V,Strambini LM,Debrassi A,Egri G,Dähne L,Barillaro G

    更新日期：2018-12-10 00:00:00

  • Versatile electrification of two-dimensional nanomaterials in water.

    abstract：:The recent emergence of nanofluidics has highlighted the exceptional properties of graphene and its boron-nitride counterpart as confining nanomaterials for water and ion transport. Surprisingly, ionic transport experiments have unveiled a consequent electrification of the water/carbon surfaces, with a contrasting res...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-09708-7

    authors： Grosjean B,Bocquet ML,Vuilleumier R

    更新日期：2019-04-10 00:00:00

  • Injectable human recombinant collagen matrices limit adverse remodeling and improve cardiac function after myocardial infarction.

    abstract：:Despite the success of current therapies for acute myocardial infarction (MI), many patients still develop adverse cardiac remodeling and heart failure. With the growing prevalence of heart failure, a new therapy is needed that can prevent remodeling and support tissue repair. Herein, we report on injectable recombina...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-12748-8

    authors： McLaughlin S,McNeill B,Podrebarac J,Hosoyama K,Sedlakova V,Cron G,Smyth D,Seymour R,Goel K,Liang W,Rayner KJ,Ruel M,Suuronen EJ,Alarcon EI

    更新日期：2019-10-25 00:00:00

  • Twin-induced one-dimensional homojunctions yield high quantum efficiency for solar hydrogen generation.

    abstract：:Efficient charge separation is of crucial importance for the improvement of photocatalytic activity for solar hydrogen evolution. Here we report efficient photo-generated charge separation by twin-induced one-dimensional homojunctions with type-II staggered band alignment, using a ternary chalcogenate, i.e. Cd0.5Zn0.5...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms3278

    authors： Liu M,Jing D,Zhou Z,Guo L

    更新日期：2013-01-01 00:00:00

  • Bromodomain and extraterminal proteins foster the core transcriptional regulatory programs and confer vulnerability in liposarcoma.

    abstract：:Liposarcomas (LPSs) are a group of malignant mesenchymal tumors showing adipocytic differentiation. Here, to gain insight into the enhancer dysregulation and transcriptional addiction in this disease, we chart super-enhancer structures in both LPS tissues and cell lines. We identify a bromodomain and extraterminal (BE...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-09257-z

    authors： Chen Y,Xu L,Mayakonda A,Huang ML,Kanojia D,Tan TZ,Dakle P,Lin RY,Ke XY,Said JW,Chen J,Gery S,Ding LW,Jiang YY,Pang A,Puhaindran ME,Goh BC,Koeffler HP

    更新日期：2019-03-22 00:00:00

  • DRP1-mediated mitochondrial shape controls calcium homeostasis and muscle mass.

    abstract：:Mitochondrial quality control is essential in highly structured cells such as neurons and muscles. In skeletal muscle the mitochondrial fission proteins are reduced in different physiopathological conditions including ageing sarcopenia, cancer cachexia and chemotherapy-induced muscle wasting. However, whether mitochon...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-10226-9

    authors： Favaro G,Romanello V,Varanita T,Andrea Desbats M,Morbidoni V,Tezze C,Albiero M,Canato M,Gherardi G,De Stefani D,Mammucari C,Blaauw B,Boncompagni S,Protasi F,Reggiani C,Scorrano L,Salviati L,Sandri M

    更新日期：2019-06-12 00:00:00

  • Electroneutrality breakdown and specific ion effects in nanoconfined aqueous electrolytes observed by NMR.

    abstract：:Ion distribution in aqueous electrolytes near the interface plays a critical role in electrochemical, biological and colloidal systems, and is expected to be particularly significant inside nanoconfined regions. Electroneutrality of the total charge inside nanoconfined regions is commonly assumed a priori in solving i...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms7358

    authors： Luo ZX,Xing YZ,Ling YC,Kleinhammes A,Wu Y

    更新日期：2015-02-20 00:00:00

  • Observations of pressure anisotropy effects within semi-collisional magnetized plasma bubbles.

    abstract：:Magnetized plasma interactions are ubiquitous in astrophysical and laboratory plasmas. Various physical effects have been shown to be important within colliding plasma flows influenced by opposing magnetic fields, however, experimental verification of the mechanisms within the interaction region has remained elusive. ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-20387-7

    authors： Tubman ER,Joglekar AS,Bott AFA,Borghesi M,Coleman B,Cooper G,Danson CN,Durey P,Foster JM,Graham P,Gregori G,Gumbrell ET,Hill MP,Hodge T,Kar S,Kingham RJ,Read M,Ridgers CP,Skidmore J,Spindloe C,Thomas AGR,Treadwe

    更新日期：2021-01-12 00:00:00

  • Quantifying net loss of global mangrove carbon stocks from 20 years of land cover change.

    abstract：:Mangrove forests hold some of the highest densities of carbon recorded in any ecosystem, but have experienced widespread deforestation through conversion to aquaculture and agriculture. Alongside deforestation, mangroves have shown simultaneous natural expansion in some parts of the world, and considerable investments...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-18118-z

    authors： Richards DR,Thompson BS,Wijedasa L

    更新日期：2020-08-26 00:00:00

  • Frustrated supercritical collapse in tunable charge arrays on graphene.

    abstract：:The photon-like behavior of electrons in graphene causes unusual confinement properties that depend strongly on the geometry and strength of the surrounding potential. We report bottom-up synthesis of atomically-precise one-dimensional (1D) arrays of point charges on graphene that allow exploration of a new type of su...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-08371-2

    authors： Lu J,Tsai HZ,Tatan AN,Wickenburg S,Omrani AA,Wong D,Riss A,Piatti E,Watanabe K,Taniguchi T,Zettl A,Pereira VM,Crommie MF

    更新日期：2019-01-29 00:00:00

  • Ultrafast photoinduced band splitting and carrier dynamics in chiral tellurium nanosheets.

    abstract：:Trigonal tellurium (Te) is a chiral semiconductor that lacks both mirror and inversion symmetries, resulting in complex band structures with Weyl crossings and unique spin textures. Detailed time-resolved polarized reflectance spectroscopy is used to investigate its band structure and carrier dynamics. The polarized t...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-17766-5

    authors： Jnawali G,Xiang Y,Linser SM,Shojaei IA,Wang R,Qiu G,Lian C,Wong BM,Wu W,Ye PD,Leng Y,Jackson HE,Smith LM

    更新日期：2020-08-10 00:00:00

  • Driving diffusionless transformations in colloidal crystals using DNA handshaking.

    abstract：:Many crystals, such as those of metals, can transform from one symmetry into another having lower free energy via a diffusionless transformation. Here we create binary colloidal crystals consisting of polymer microspheres, pulled together by DNA bridges, that induce specific, reversible attractions between two species...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms2206

    authors： Casey MT,Scarlett RT,Rogers WB,Jenkins I,Sinno T,Crocker JC

    更新日期：2012-01-01 00:00:00

  • The iBeetle large-scale RNAi screen reveals gene functions for insect development and physiology.

    abstract：:Genetic screens are powerful tools to identify the genes required for a given biological process. However, for technical reasons, comprehensive screens have been restricted to very few model organisms. Therefore, although deep sequencing is revealing the genes of ever more insect species, the functional studies predom...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms8822

    authors： Schmitt-Engel C,Schultheis D,Schwirz J,Ströhlein N,Troelenberg N,Majumdar U,Dao VA,Grossmann D,Richter T,Tech M,Dönitz J,Gerischer L,Theis M,Schild I,Trauner J,Koniszewski ND,Küster E,Kittelmann S,Hu Y,Lehmann S,S

    更新日期：2015-07-28 00:00:00

  • Multistep assembly of DNA condensation clusters by SMC.

    abstract：:SMC (structural maintenance of chromosomes) family members play essential roles in chromosome condensation, sister chromatid cohesion and DNA repair. It remains unclear how SMCs structure chromosomes and how their mechanochemical cycle regulates their interactions with DNA. Here we used single-molecule fluorescence mi...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms10200

    authors： Kim H,Loparo JJ

    更新日期：2016-01-04 00:00:00

  • Arabidopsis uses two gluconeogenic gateways for organic acids to fuel seedling establishment.

    abstract：:Gluconeogenesis is a fundamental metabolic process that allows organisms to make sugars from non-carbohydrate stores such as lipids and protein. In eukaryotes only one gluconeogenic route has been described from organic acid intermediates and this relies on the enzyme phosphoenolpyruvate carboxykinase (PCK). Here we s...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms7659

    authors： Eastmond PJ,Astley HM,Parsley K,Aubry S,Williams BP,Menard GN,Craddock CP,Nunes-Nesi A,Fernie AR,Hibberd JM

    更新日期：2015-04-10 00:00:00

  • Long-lasting severe immune dysfunction in Ebola virus disease survivors.

    abstract：:Long-term follow up studies from Ebola virus disease (EVD) survivors (EBOV_S) are lacking. Here, we evaluate immune and gene expression profiles in 35 Guinean EBOV_S from the last West African outbreak, a median of 23 months (IQR [18-25]) after discharge from treatment center. Compared with healthy donors, EBOV_S exhi...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-17489-7

    authors： Wiedemann A,Foucat E,Hocini H,Lefebvre C,Hejblum BP,Durand M,Krüger M,Keita AK,Ayouba A,Mély S,Fernandez JC,Touré A,Fourati S,Lévy-Marchal C,Raoul H,Delaporte E,Koivogui L,Thiébaut R,Lacabaratz C,Lévy Y,PostEboGui

    更新日期：2020-07-24 00:00:00

  • A mechanistic theory for aquatic food chain length.

    abstract：:Multiple hypotheses propose an ostensibly disparate array of drivers of food chain length (FCL), with contradictory support from natural settings. Here we posit that the magnitude of vertical energy flux in food webs underlies several drivers of FCL. We show that rising energy flux fuels top-heavy biomass pyramids, pr...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-02157-0

    authors： Ward CL,McCann KS

    更新日期：2017-12-11 00:00:00

  • Pyruvate kinase type M2 promotes tumour cell exosome release via phosphorylating synaptosome-associated protein 23.

    abstract：:Tumour cells secrete exosomes that are involved in the remodelling of the tumour-stromal environment and promoting malignancy. The mechanisms governing tumour exosome release, however, remain incompletely understood. Here we show that tumour cell exosomes secretion is controlled by pyruvate kinase type M2 (PKM2), whic...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms14041

    authors： Wei Y,Wang D,Jin F,Bian Z,Li L,Liang H,Li M,Shi L,Pan C,Zhu D,Chen X,Hu G,Liu Y,Zhang CY,Zen K

    更新日期：2017-01-09 00:00:00

  • Switchable photovoltaic windows enabled by reversible photothermal complex dissociation from methylammonium lead iodide.

    abstract：:Materials with switchable absorption properties have been widely used for smart window applications to reduce energy consumption and enhance occupant comfort in buildings. In this work, we combine the benefits of smart windows with energy conversion by producing a photovoltaic device with a switchable absorber layer t...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-01842-4

    authors： Wheeler LM,Moore DT,Ihly R,Stanton NJ,Miller EM,Tenent RC,Blackburn JL,Neale NR

    更新日期：2017-11-23 00:00:00

  • Turning a native or corroded Mg alloy surface into an anti-corrosion coating in excited CO2.

    abstract：:Despite their energy-efficient merits as promising light-weight structural materials, magnesium (Mg) based alloys suffer from inadequate corrosion resistance. One primary reason is that the native surface film on Mg formed in air mainly consists of Mg(OH)2 and MgO, which is porous and unprotective, especially in humid...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-06433-5

    authors： Wang Y,Liu B,Zhao X,Zhang X,Miao Y,Yang N,Yang B,Zhang L,Kuang W,Li J,Ma E,Shan Z

    更新日期：2018-10-03 00:00:00

  • Interrogating the protein interactomes of RAS isoforms identifies PIP5K1A as a KRAS-specific vulnerability.

    abstract：:In human cancers, oncogenic mutations commonly occur in the RAS genes KRAS, NRAS, or HRAS, but there are no clinical RAS inhibitors. Mutations are more prevalent in KRAS, possibly suggesting a unique oncogenic activity mediated by KRAS-specific interaction partners, which might be targeted. Here, we determine the spec...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-05692-6

    authors： Adhikari H,Counter CM

    更新日期：2018-09-07 00:00:00

  • Size-dependent kinetics during non-equilibrium lithiation of nano-sized zinc ferrite.

    abstract：:Spinel transition metal oxides (TMOs) have emerged as promising anode materials for lithium-ion batteries. It has been shown that reducing their particle size to nanoscale dimensions benefits overall electrochemical performance. Here, we use in situ transmission electron microscopy to probe the lithiation behavior of ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-07831-5

    authors： Li J,Meng Q,Zhang Y,Peng L,Yu G,Marschilok AC,Wu L,Su D,Takeuchi KJ,Takeuchi ES,Zhu Y,Stach EA

    更新日期：2019-01-09 00:00:00

  • Highly efficient oxygen evolution reaction via facile bubble transport realized by three-dimensionally stack-printed catalysts.

    abstract：:Despite highly promising characteristics of three-dimensionally (3D) nanostructured catalysts for the oxygen evolution reaction (OER) in polymer electrolyte membrane water electrolyzers (PEMWEs), universal design rules for maximizing their performance have not been explored. Here we show that woodpile (WP)-structured ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-18686-0

    authors： Kim YJ,Lim A,Kim JM,Lim D,Chae KH,Cho EN,Han HJ,Jeon KU,Kim M,Lee GH,Lee GR,Ahn HS,Park HS,Kim H,Kim JY,Jung YS

    更新日期：2020-10-01 00:00:00