Formation, Microstructure, and Conductivity of a Novel Ga2S3-Sb2S3-AgI Chalcogenide System.

Abstract:

:Novel glasses in a Ga2S3-Sb2S3-AgI system were prepared with a melt-quenching method, and their glass-forming region was identified. The maximum dissolvable AgI in glasses was 65 mol%. The thermal, optical, and structural properties of glasses were investigated as a function of AgI and Ga2S3 contents. The Ga2S3-Sb2S3-AgI glasses possess a wide region of transmission window (0.65-14 μm). An ionic conductivity of approximately 1.01 × 10-3 S/cm can be obtained for a 40 (0.8Sb2S3-0.2Ga2S3)-60AgI glass at an ambient temperature, and the ionic conductivity increased as temperature increased. The relative activation energy of Ag+ conduction was also calculated. These novel glasses show potential for the combined application of infrared optics and solid electrolytes.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Huang X,Jiao Q,Lin C,Ma H,Zhang X,Zhu E,Liu X,Dai S,Xu T

doi

10.1038/s41598-018-20144-3

subject

Has Abstract

pub_date

2018-01-26 00:00:00

pages

1699

issue

1

issn

2045-2322

pii

10.1038/s41598-018-20144-3

journal_volume

8

pub_type

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