Measuring molecular frequencies in the 1-10 μm range at 11-digits accuracy.

Abstract:

:High-resolution spectroscopy in the 1-10 μm region has never been fully tackled for the lack of widely-tunable and practical light sources. Indeed, all solutions proposed thus far suffer from at least one of three issues: they are feasible only in a narrow spectral range; the power available for spectroscopy is limited; the frequency accuracy is poor. Here, we present a setup for high-resolution spectroscopy, whose approach can be applied in the whole 1-10 μm range. It combines the power of quantum cascade lasers (QCLs) and the accuracy achievable by difference frequency generation using an orientation patterned GaP crystal. The frequency is measured against a primary frequency standard using the Italian metrological fibre link network. We demonstrate the performance of the setup by measuring a vibrational transition in a highly-excited metastable state of CO around 6 μm with 11 digits of precision.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Insero G,Borri S,Calonico D,Pastor PC,Clivati C,D'Ambrosio D,De Natale P,Inguscio M,Levi F,Santambrogio G

doi

10.1038/s41598-017-12891-6

subject

Has Abstract

pub_date

2017-10-06 00:00:00

pages

12780

issue

1

issn

2045-2322

pii

10.1038/s41598-017-12891-6

journal_volume

7

pub_type

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