Abstract:
:Polydiacetylene (PDA) vesicles have been applied as optical sensors in different areas, although there are difficulties in controlling their responses. In this study, we prepared nanoblends of PDA with triblock copolymers (TC) as a better sensor system for detecting temperature change. The influences of diacetylene (DA) monomer, and the TC chemical structure and concentration on the colorimetric response (CR) were examined. The TC/PDA nanoblend was remarkably more sensitive to temperature change, than classical vesicles. A higher L64 concentration of 12.0% (w/w) reduced the chromatic transition temperature (Ttr) to as low as 24°C. When using different TCs, the Ttr values can be ordered as L35 journal_name journal_title authors doi subject pub_date pages eissn issn pii journal_volume pub_type
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