Design of (Nb, Mo)40Ti30Ni30 alloy membranes for combined enhancement of hydrogen permeability and embrittlement resistance.

Abstract:

:The effect of substitution of Nb by Mo in Nb40Ti30Ni30 was investigated with respect to microstructural features and hydrogen dissolution, diffusion and permeation. As-cast Nb40-xMoxTi30Ni30 (x = 0, 5, 10) alloys consist of primary bcc-Nb phase and binary eutectic (bcc-Nb + B2-TiNi). The substitution of Nb by Mo reduces the hydrogen solubility in alloys, but may increase (x = 5) or decrease (x = 10) the apparent hydrogen diffusivity and permeability. As-cast Nb35Mo5Ti30Ni30 exhibits a combined enhancement of hydrogen permeability and embrittlement resistance as compared to Nb40Ti30Ni30. This work confirms that Mo is a desirable alloying element in Nb that can contribute to a reduction in hydrogen absorption and an increase in intrinsic hydrogen diffusion, thus improving embrittlement resistance with minimal permeability penalty.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Li X,Liang X,Liu D,Chen R,Huang F,Wang R,Rettenmayr M,Su Y,Guo J,Fu H

doi

10.1038/s41598-017-00335-0

subject

Has Abstract

pub_date

2017-03-16 00:00:00

pages

209

issue

1

issn

2045-2322

pii

10.1038/s41598-017-00335-0

journal_volume

7

pub_type

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