Instant detection and identification of concealed explosive-related compounds: Induced Stokes Raman versus infrared.

Abstract:

:The instant detection of explosives and explosive-related compounds has become an urgent priority in recent years for homeland security and counter-terrorism applications. Modern techniques should offer enhancement in selectivity, sensitivity, and standoff distances. Miniaturisation, portability, and field-ruggedisation are crucial requirements. This study reports on instant and standoff identification of concealed explosive-related compounds using customized Raman technique. Stokes Raman spectra of common explosive-related compounds were generated and spectrally resolved to create characteristic finger print spectra. The scattered Raman emissions over the band 400:2000cm-1 were compared to infrared absorption using FTIR. It has been demonstrated that the two vibrational spectroscopic techniques were opposite and completing each other. Molecular vibrations with strong absorption in infrared (those involve strong change in dipole moments) induced weak signals in Raman and vice versa. The tailored Raman offered instant detection, high sensitivity, and standoff detection capabilities. Raman demonstrated characteristic fingerprint spectra with stable baseline and sharp intense peaks. Complete correlations of absorption/scattered signals to certain molecular vibrations were conducted to generate an entire spectroscopic profile of explosive-related compounds. This manuscript shades the light on Raman as one of the prevailing technologies for instantaneous detection of explosive-related compounds.

journal_name

Forensic Sci Int

authors

Elbasuney S,El-Sherif AF

doi

10.1016/j.forsciint.2016.11.036

subject

Has Abstract

pub_date

2017-01-01 00:00:00

pages

83-90

eissn

0379-0738

issn

1872-6283

pii

S0379-0738(16)30521-7

journal_volume

270

pub_type

杂志文章
  • Body-packing as cause of unexpected sudden death.

    abstract::Four fatalities related to smuggling of drugs by body-packing were investigated. The victims were examined at the Institute of Forensic Medicine of Hamburg University between 1983 and 1995, two of them due to "sudden" unknown cause of death. All victims were male. Two of them were found already dead in a backyard and ...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/s0379-0738(97)00192-8

    authors: Heinemann A,Miyaishi S,Iwersen S,Schmoldt A,Püschel K

    更新日期:1998-03-02 00:00:00

  • The evolution of DNA databases--recommendations for new European STR loci.

    abstract::Following a recent meeting by the ENFSI and EDNAP groups on the 4-5 April, 2005, in Glasgow, UK, it was unanimously agreed that the process of standardization within Europe should take account of recent work that unequivocally demonstrated that chance of obtaining a result from a degraded sample was increased when sma...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2005.05.036

    authors: Gill P,Fereday L,Morling N,Schneider PM

    更新日期:2006-01-27 00:00:00

  • Typing of 20 Y-chromosome STRs in the Italian population.

    abstract::The aim of the present study is to appraise the increase of the discrimination power of the Y-specific haplotype allowed by 20 STR markers in a sample of the Italian population. The set of Y STR markers analyzed includes the European "extended haplotype" DYS19, DYS385, DYS389I/II, DYS390, DYS391, DYS392, DYS393 and YC...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2004.09.041

    authors: Biondo R,Caglià A,Asili P,D'Agostaro G,D'Agostino G,Spinella A

    更新日期:2004-12-02 00:00:00

  • Children and guns: The detection of recent contact with firearms on children's hands by the PDT reagent.

    abstract::Throughout the world, young children are worryingly found to be involved in both unintentional and intentional gun violence, rendering the forensic investigation of gun handling by children a highly important matter. The effectiveness of the PDT reaction for mapping iron traces on hands of children has been tested and...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2015.05.008

    authors: Bar-Or KL,Almog J

    更新日期:2015-08-01 00:00:00

  • Densely calculated facial soft tissue thickness for craniofacial reconstruction in Chinese adults.

    abstract::Craniofacial reconstruction (CFR) is used to recreate a likeness of original facial appearance for an unidentified skull; this technique has been applied in both forensics and archeology. Many CFR techniques rely on the average facial soft tissue thickness (FSTT) of anatomical landmarks, related to ethnicity, age, sex...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2016.07.017

    authors: Shui W,Zhou M,Deng Q,Wu Z,Ji Y,Li K,He T,Jiang H

    更新日期:2016-09-01 00:00:00

  • Suicide through doxylamine poisoning.

    abstract::Doxylamine is an antihistamine of the ethanolamine class. It is used primarily as a sleep-inducing agent. Only a few reports can be found in the literature about lethal intoxications with doxylamine, but many with combined intoxications. Doxylamine is, aside from diphenhydramine, the only chemically defined active ing...

    journal_title:Forensic science international

    pub_type: 杂志文章,评审

    doi:10.1016/s0379-0738(00)00393-5

    authors: Bockholdt B,Klug E,Schneider V

    更新日期:2001-06-01 00:00:00

  • Bayesian analysis of fingerprint, face and signature evidences with automatic biometric systems.

    abstract::The Bayesian approach provides a unified and logical framework for the analysis of evidence and to provide results in the form of likelihood ratios (LR) from the forensic laboratory to court. In this contribution we want to clarify how the biometric scientist or laboratory can adapt their conventional biometric system...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2004.11.007

    authors: Gonzalez-Rodriguez J,Fierrez-Aguilar J,Ramos-Castro D,Ortega-Garcia J

    更新日期:2005-12-20 00:00:00

  • The recovery of latent fingermarks and DNA using a silicone-based casting material.

    abstract::There are many techniques available for the recovery of fingermarks at scenes of crime including the possibility of taking casts of the marks. Casts can be advantageous in cases where other destructive recovery techniques might not be suitable, such as when recovering finger marks deposited on valued or immobile items...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2008.04.001

    authors: Shalhoub R,Quinones I,Ames C,Multaney B,Curtis S,Seeboruth H,Moore S,Daniel B

    更新日期:2008-07-04 00:00:00

  • Ultra-high-performance liquid chromatography tandem mass spectrometry determination of GHB, GHB-glucuronide in plasma and cerebrospinal fluid of narcoleptic patients under sodium oxybate treatment.

    abstract::Sodium oxybate (Xyrem®), the sodium salt of γ- hydroxybutyric acid (GHB), is a first-line treatment of the symptoms induced by type 1 narcolepsy (NT1) and it is highly effective in improving sleep architecture, decreasing excessive daytime sleepiness and the frequency of cataplexy attacks. Using an ultra-high-performa...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2017.01.015

    authors: Tittarelli R,Pichini S,Pedersen DS,Pacifici R,Moresco M,Pizza F,Busardò FP,Plazzi G

    更新日期:2017-05-01 00:00:00

  • ABO tissue antigens of Egyptian mummies.

    abstract::ABO groups were investigated on skin (and muscle), bone and hair specimens from 14 Egyptian mummies dating from the Roman period. Samples were tested by the AE (absorption-elution), MA (mixed agglutination) and HIF (histo-immunofluorescence) methods, in order to evaluate the reliability of each method. For half of the...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/0379-0738(89)90130-8

    authors: Crainic K,Durigon M,Oriol R

    更新日期:1989-10-01 00:00:00

  • Head injuries of Roman gladiators.

    abstract::Gladiator remains from a recently unearthed cemetery in ancient Ephesus (Turkey) offer a unique opportunity for proving common theories involving the weaponry and techniques of gladiator fighting based on the evidence supplied by cranial bones. This mass grave is the first of its kind to undergo a thorough osteologica...

    journal_title:Forensic science international

    pub_type: 历史文章,杂志文章

    doi:10.1016/j.forsciint.2005.10.010

    authors: Kanz F,Grossschmidt K

    更新日期:2006-07-13 00:00:00

  • Fatal intoxications in a Swedish forensic autopsy material during 1992-2002.

    abstract::Compilations of substances detected in fatal intoxications are important in order to observe changes in intoxication patterns, to monitor effects of preventive work and to discover new trends in drug usage. The aim of the present study was to describe the current pattern of substances detected in fatal intoxications i...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2004.02.010

    authors: Jönsson A,Holmgren P,Ahlner J

    更新日期:2004-06-30 00:00:00

  • Virtual assessment of perimortem and postmortem blunt force cranial trauma.

    abstract::The aim of this study is to investigate the potential use of reconstructed three-dimensional multi-detector computed tomography (3D MDCT) imagery to distinguish between perimortem cranial trauma and postmortem cranial damage. A total of 45 crania were initially examined for the purpose of this study. The postmortem gr...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2013.03.032

    authors: Fleming-Farrell D,Michailidis K,Karantanas A,Roberts N,Kranioti EF

    更新日期:2013-06-10 00:00:00

  • Molecular genetic basis of red cell markers and its forensic application.

    abstract::(1) The polymerase chain reaction (PCR) was used to amplify Rh-related cDNAs from erythroid cells cultured by the selective two-phase liquid culture system for human erythroid progenitors in peripheral blood. Two Rh polypeptide cDNAs have been isolated from the PCR products and tentatively designated RhPI cDNA and RhP...

    journal_title:Forensic science international

    pub_type: 杂志文章,评审

    doi:10.1016/0379-0738(96)01935-4

    authors: Ikemoto S,Iwamoto S,Tsuchida S,Goto K,Oyamada T,Kajii E

    更新日期:1996-06-28 00:00:00

  • Variability of fingerprint ridge density in a sample of Spanish Caucasians and its application to sex determination.

    abstract::Despite the fact that the differences in epidermal ridge density between men and women have been accepted for some time, they have only been thoroughly demonstrated in a small number of populations. The aim of this study is to determine whether such differences exist in a sample of the Spanish population by counting e...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2008.06.014

    authors: Gutiérrez-Redomero E,Alonso C,Romero E,Galera V

    更新日期:2008-08-25 00:00:00

  • Hair combing to collect organic gunshot residues (OGSR).

    abstract::A protocol is presented for the collection and analysis of gunshot residues (GSR) from hair. A fine-toothed comb is used for collection of the residues. A small zip-closure bag serves as a container for both sample storage and extraction of the characteristic organic powder additives. The success of this residue recov...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/s0379-0738(03)00207-x

    authors: MacCrehan WA,Layman MJ,Secl JD

    更新日期:2003-08-12 00:00:00

  • Fracture analysis of tube boiler for physical explosion accident.

    abstract::Material and failure analysis techniques are key tools for determining causation in case of explosive and bursting accident result from material and process defect of product in the field of forensic science. The boiler rupture generated by defect of the welding division, corrosion, overheating and degradation of the ...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2017.07.036

    authors: Kim ES

    更新日期:2017-09-01 00:00:00

  • Hair analysis for nicotine and cotinine: evaluation of extraction procedures, hair treatments, and development of reference material.

    abstract::Analysis of nicotine and cotinine in human hair can provide information on nicotine intake and exposure to environmental tobacco smoke over a long period of time. Nonetheless, to better assess the usefulness of hair analysis to determine smoking habits or exposures, all procedures have to be standardized. Various solv...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/s0379-0738(96)02068-3

    authors: Pichini S,Altieri I,Pellegrini M,Pacifici R,Zuccaro P

    更新日期:1997-01-17 00:00:00

  • Chemical profiling of the street cocktail drug 'nyaope' in South Africa using GC-MS II: Stability studies of the cannabinoid, opiate and antiretroviral components during sample storage.

    abstract::Nyaope is a mixture of low grade heroin, cannabis products, antiretroviral drugs and other materials added as bulking agents. It is a highly physically additive mixture which is smoked by users. As part of the development of a method for the analysis and profiling of nyaope this study evaluates the stability of the ca...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2019.04.040

    authors: Mthembi PM,Mwenesongole EM,Cole MD

    更新日期:2019-07-01 00:00:00

  • Testing the utility of a geographical profiling approach in three rape series of a single offender: a case study.

    abstract::The purpose of the study was to test the potential utility of a geographical profiling approach for three separate series of rapes committed by a single offender. Two different mathematical distance-decay functions using either a normal distribution with a mean distance and standard deviation based on previous researc...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/s0379-0738(02)00385-7

    authors: Santtila P,Zappalà A,Laukkanen M,Picozzi M

    更新日期:2003-01-09 00:00:00

  • Evaluation of the correlation between time corpses spent in in-ground graves and findings at exhumation.

    abstract::To determine how long pathological findings persist after burial and which factors play a role in decomposition of a corpse, we evaluated all bodies exhumed under the auspices of the Institute of Legal Medicine at the Hannover Medical School between 1978 and 1997. A total of 87 exhumations (54 men, 33 women) were perf...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2004.11.018

    authors: Breitmeier D,Graefe-Kirci U,Albrecht K,Weber M,Tröger HD,Kleemann WJ

    更新日期:2005-11-25 00:00:00

  • Allele frequency distribution of four PCR-amplified loci in the Spanish population.

    abstract::The allele frequency distributions of four VNTR loci amplified by PCR have been studied in a population of 205 individuals from Spain. The loci analysed are D1S80 and three STRs: HUMTH01, HUMFES/FPS and HUMACTBF2 (SE33). The former was visualized in Metaphor agarose gels, and the STRs in sequencing polyacrylamide gels...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/0379-0738(94)01661-n

    authors: Cabrero C,Díez A,Valverde E,Carracedo A,Alemany J

    更新日期:1995-01-30 00:00:00

  • Development of application protocols of the Emit® II Plus 6-Acetylmorphine Assay on the ADVIA® 1800 and 2400 Chemistry Systems.

    abstract::New application protocols for the Emit(®) II Plus 6-Acetylmorphine Assay for human urine screening have been developed on the ADVIA(®) 1800 and 2400 Chemistry Systems. Precision was evaluated at the cutoff and ±25% controls. Recovery and linearity were studied by spiking 6-acetylmorphine (6-AM) into human urine pools....

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2014.08.014

    authors: Warren JA,Siefring G Jr,Morjana N

    更新日期:2014-11-01 00:00:00

  • Uncertainty about the true source. A note on the likelihood ratio at the activity level.

    abstract::This paper focuses on likelihood ratio based evaluations of fibre evidence in cases in which there is uncertainty about whether or not the reference item available for analysis - that is, an item typically taken from the suspect or seized at his home - is the item actually worn at the time of the offence. A likelihood...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2012.02.021

    authors: Taroni F,Biedermann A,Bozza S,Comte J,Garbolino P

    更新日期:2012-07-10 00:00:00

  • A method for sex estimation using the proximal femur.

    abstract::The assessment of sex is crucial to the establishment of a biological profile of an unidentified skeletal individual. The best methods currently available for the sexual diagnosis of human skeletal remains generally rely on the presence of well-preserved pelvic bones, which is not always the case. Postcranial elements...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2016.06.011

    authors: Curate F,Coelho J,Gonçalves D,Coelho C,Ferreira MT,Navega D,Cunha E

    更新日期:2016-09-01 00:00:00

  • Unexpected natural death secondary to intra-abdominal bleeding: report of one idiopathic spontaneous intraperitoneal hemorrhage case.

    abstract::A 39-year-old woman was found dead at home. She was single, foreign national, chronic alcoholic, and had given shelter to a compatriot for three days. This man found the deceased in her bed, after a night of heavy drinking. The emergency medical team observed numerous recent blue ecchymoses of the upper limbs. Because...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2011.08.004

    authors: Dedouit F,Piercecchi-Marti MD,Leonetti G,Rougé D,Telmon N

    更新日期:2012-01-10 00:00:00

  • Clinical applications of hair testing for drugs of abuse--the Canadian experience.

    abstract::During the last 2 decades there has been a substantial increase in illicit drug consumption in North America. It has been repeatedly shown that the personal history of drug use is far from being accurate. Fearing legal consequences and embarrassment of admitted illicit substance use, most users tend to deny or, to und...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/s0379-0738(99)00171-1

    authors: Klein J,Karaskov T,Koren G

    更新日期:2000-01-10 00:00:00

  • Sexual dimorphism of ossified costal cartilage. Radiograph scan study on Caucasian men and women (Czech population).

    abstract::The aim of our study was to evaluate differences between males and females based on patterns of costal cartilage ossification and also with respect to ageing. We provided diagnosis of ossifications from two files of radiograms. The first group consisted of 1044 chest and abdominal radiograms of patients (537 men and 5...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2009.06.009

    authors: Rejtarová O,Hejna P,Rejtar P,Bukac J,Slízová D,Krs O

    更新日期:2009-10-30 00:00:00

  • Effect of yarn structure on wicking and its impact on bloodstain pattern analysis (BPA) on woven cotton fabrics.

    abstract::Bloodstain pattern analysis (BPA) of bloodstains on hard, non-porous surfaces has found widespread use in crime scene analysis and reconstruction for violent crimes in which bloodshed occurs. At many violent crime scenes, bloody clothing is also found and may be analyzed. However, to date, there are no definitive meth...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2017.04.011

    authors: Li X,Li J,Michielsen S

    更新日期:2017-07-01 00:00:00

  • Genital and anal injuries: A cross-sectional Australian study of 1266 women alleging recent sexual assault.

    abstract:OBJECTIVES:To describe the frequency of genital and anal injury and associated demographic and assault characteristics in women alleging sexual assault. DESIGN:Cross-sectional study. SETTING:Sexual Assault Resource Centre (SARC), Western Australia. PARTICIPANTS:Total of 1266 women attending SARC from Jan-2009 to Mar...

    journal_title:Forensic science international

    pub_type: 杂志文章

    doi:10.1016/j.forsciint.2017.03.013

    authors: Zilkens RR,Smith DA,Phillips MA,Mukhtar SA,Semmens JB,Kelly MC

    更新日期:2017-06-01 00:00:00