当前位置： SCI文献检索 > Nature Communications期刊下所有文献 > Cobalt-centred boron molecular drums with the highest coordination number in the CoB16- cluster.

Cobalt-centred boron molecular drums with the highest coordination number in the CoB16- cluster.

Abstract：

:The electron deficiency and strong bonding capacity of boron have led to a vast variety of molecular structures in chemistry and materials science. Here we report the observation of highly symmetric cobalt-centered boron drum-like structures of CoB16(-), characterized by photoelectron spectroscopy and ab initio calculations. The photoelectron spectra display a relatively simple spectral pattern, suggesting a high symmetry structure. Two nearly degenerate isomers with D8d (I) and C4v (II) symmetries are found computationally to compete for the global minimum. These drum-like structures consist of two B8 rings sandwiching a cobalt atom, which has the highest coordination number known heretofore in chemistry. We show that doping of boron clusters with a transition metal atom induces an earlier two-dimensional to three-dimensional structural transition. The CoB16(-) cluster is tested as a building block in a triple-decker sandwich, suggesting a promising route for its realization in the solid state.

journal_name

Nat Commun

journal_title

Nature communications

authors

Popov IA,Jian T,Lopez GV,Boldyrev AI,Wang LS

doi

10.1038/ncomms9654

subject

Has Abstract

pub_date

2015-10-12 00:00:00

pages

8654

issn

2041-1723

pii

ncomms9654

journal_volume

6

pub_type

杂志文章

相关文献

Nature Communications文献大全
  • Multi-scale characterisation of a ferroelectric polymer reveals the emergence of a morphological phase transition driven by temperature.

    abstract：:Ferroelectric materials exhibit a phase transition to a paraelectric state driven by temperature - called the Curie transition. In conventional ferroelectrics, the Curie transition is caused by a change in crystal symmetry, while the material itself remains a continuous three-dimensional solid crystal. However, ferroe...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-20407-6

    authors： Hafner J,Benaglia S,Richheimer F,Teuschel M,Maier FJ,Werner A,Wood S,Platz D,Schneider M,Hradil K,Castro FA,Garcia R,Schmid U

    更新日期：2021-01-08 00:00:00

  • Low-dose penicillin in early life induces long-term changes in murine gut microbiota, brain cytokines and behavior.

    abstract：:There is increasing concern about potential long-term effects of antibiotics on children's health. Epidemiological studies have revealed that early-life antibiotic exposure can increase the risk of developing immune and metabolic diseases, and rodent studies have shown that administration of high doses of antibiotics ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms15062

    authors： Leclercq S,Mian FM,Stanisz AM,Bindels LB,Cambier E,Ben-Amram H,Koren O,Forsythe P,Bienenstock J

    更新日期：2017-04-04 00:00:00

  • The Atg1-kinase complex tethers Atg9-vesicles to initiate autophagy.

    abstract：:Autophagosomes are double-membrane vesicles that sequester cytoplasmic material for lysosomal degradation. Their biogenesis is initiated by recruitment of Atg9-vesicles to the phagophore assembly site. This process depends on the regulated activation of the Atg1-kinase complex. However, the underlying molecular mechan...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms10338

    authors： Rao Y,Perna MG,Hofmann B,Beier V,Wollert T

    更新日期：2016-01-12 00:00:00

  • Islands contribute disproportionately high amounts of evolutionary diversity in passerine birds.

    abstract：:Island systems generally have fewer species than continental areas due to their small size and geographical isolation. Low island diversity reduces the possibility of exportation of island lineages and island systems are not thought to have a major influence on the build-up of continental diversity. However, the view ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms9538

    authors： Jønsson KA,Holt BG

    更新日期：2015-10-05 00:00:00

  • Interference between overlapping memories is predicted by neural states during learning.

    abstract：:One of the primary contributors to forgetting is interference from overlapping memories. Intuitively, this suggests-and prominent theoretical models argue-that memory interference is best avoided by encoding overlapping memories as if they were unrelated. It is therefore surprising that reactivation of older memories ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-13377-x

    authors： Chanales AJH,Dudukovic NM,Richter FR,Kuhl BA

    更新日期：2019-11-25 00:00:00

  • Macromolecular-clustered facial amphiphilic antimicrobials.

    abstract：:Bacterial infections and antibiotic resistance, particularly by Gram-negative pathogens, have become a global healthcare crisis. We report the design of a class of cationic antimicrobial polymers that cluster local facial amphiphilicity from repeating units to enhance interactions with bacterial membranes without requ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-07651-7

    authors： Rahman MA,Bam M,Luat E,Jui MS,Ganewatta MS,Shokfai T,Nagarkatti M,Decho AW,Tang C

    更新日期：2018-12-07 00:00:00

  • Age-specific biological and molecular profiling distinguishes paediatric from adult acute myeloid leukaemias.

    abstract：:Acute myeloid leukaemia (AML) affects children and adults of all ages. AML remains one of the major causes of death in children with cancer and for children with AML relapse is the most common cause of death. Here, by modelling AML in vivo we demonstrate that AML is discriminated by the age of the cell of origin. Youn...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-07584-1

    authors： Chaudhury S,O'Connor C,Cañete A,Bittencourt-Silvestre J,Sarrou E,Prendergast Á,Choi J,Johnston P,Wells CA,Gibson B,Keeshan K

    更新日期：2018-12-11 00:00:00

  • Codoping titanium dioxide nanowires with tungsten and carbon for enhanced photoelectrochemical performance.

    abstract：:Recent density-functional theory calculations suggest that codoping TiO2 with donor-acceptor pairs is more effective than monodoping for improving photoelectrochemical water-splitting performance because codoping can reduce charge recombination, improve material quality, enhance light absorption and increase solubilit...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms2729

    authors： Cho IS,Lee CH,Feng Y,Logar M,Rao PM,Cai L,Kim DR,Sinclair R,Zheng X

    更新日期：2013-01-01 00:00:00

  • IL-17-producing γδ T cells enhance bone regeneration.

    abstract：:Immune responses are crucial not only for host defence against pathogens but also for tissue maintenance and repair after injury. Lymphocytes are involved in the healing process after tissue injury, including bone fracture and muscle damage. However, the specific immune cell subsets and mediators of healing are not en...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms10928

    authors： Ono T,Okamoto K,Nakashima T,Nitta T,Hori S,Iwakura Y,Takayanagi H

    更新日期：2016-03-11 00:00:00

  • Precise radiometric age establishes Yarrabubba, Western Australia, as Earth's oldest recognised meteorite impact structure.

    abstract：:The ~70 km-diameter Yarrabubba impact structure in Western Australia is regarded as among Earth's oldest, but has hitherto lacked precise age constraints. Here we present U-Pb ages for impact-driven shock-recrystallised accessory minerals. Shock-recrystallised monazite yields a precise impact age of 2229 ± 5 Ma, coeva...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-13985-7

    authors： Erickson TM,Kirkland CL,Timms NE,Cavosie AJ,Davison TM

    更新日期：2020-01-21 00:00:00

  • Ion antiport accelerates photosynthetic acclimation in fluctuating light environments.

    abstract：:Many photosynthetic organisms globally, including crops, forests and algae, must grow in environments where the availability of light energy fluctuates dramatically. How photosynthesis maintains high efficiency despite such fluctuations in its energy source remains poorly understood. Here we show that Arabidopsis thal...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms6439

    authors： Armbruster U,Carrillo LR,Venema K,Pavlovic L,Schmidtmann E,Kornfeld A,Jahns P,Berry JA,Kramer DM,Jonikas MC

    更新日期：2014-11-13 00:00:00

  • Tornado outbreak variability follows Taylor's power law of fluctuation scaling and increases dramatically with severity.

    abstract：:Tornadoes cause loss of life and damage to property each year in the United States and around the world. The largest impacts come from 'outbreaks' consisting of multiple tornadoes closely spaced in time. Here we find an upward trend in the annual mean number of tornadoes per US tornado outbreak for the period 1954-201...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms10668

    authors： Tippett MK,Cohen JE

    更新日期：2016-02-29 00:00:00

  • Gut microbiome-related effects of berberine and probiotics on type 2 diabetes (the PREMOTE study).

    abstract：:Human gut microbiome is a promising target for managing type 2 diabetes (T2D). Measures altering gut microbiota like oral intake of probiotics or berberine (BBR), a bacteriostatic agent, merit metabolic homoeostasis. We hence conducted a randomized, double-blind, placebo-controlled trial with newly diagnosed T2D patie...

    journal_title：Nature communications

    pub_type： 杂志文章,随机对照试验

    doi：10.1038/s41467-020-18414-8

    authors： Zhang Y,Gu Y,Ren H,Wang S,Zhong H,Zhao X,Ma J,Gu X,Xue Y,Huang S,Yang J,Chen L,Chen G,Qu S,Liang J,Qin L,Huang Q,Peng Y,Li Q,Wang X,Kong P,Hou G,Gao M,Shi Z,Li X,Qiu Y,Zou Y,Yang H,Wang J,Xu G,

    更新日期：2020-10-06 00:00:00

  • Atomic-level characterization of transport cycle thermodynamics in the glycerol-3-phosphate:phosphate antiporter.

    abstract：:Membrane transporters actively translocate their substrate by undergoing large-scale structural transitions between inward- (IF) and outward-facing (OF) states ('alternating-access' mechanism). Despite extensive structural studies, atomic-level mechanistic details of such structural transitions, and as importantly, th...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms9393

    authors： Moradi M,Enkavi G,Tajkhorshid E

    更新日期：2015-09-29 00:00:00

  • The interdependent network of gene regulation and metabolism is robust where it needs to be.

    abstract：:Despite being highly interdependent, the major biochemical networks of the living cell-the networks of interacting genes and of metabolic reactions, respectively-have been approached mostly as separate systems so far. Recently, a framework for interdependent networks has emerged in the context of statistical physics. ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-00587-4

    authors： Klosik DF,Grimbs A,Bornholdt S,Hütt MT

    更新日期：2017-09-14 00:00:00

  • Author Correction: Improved genome recovery and integrated cell-size analyses of individual uncultured microbial cells and viral particles.

    abstract：:The original version of this Article contained errors in the units of concentration of three reagents listed in the Methods. These errors have all been corrected in both the PDF and HTML versions of the Article. ...

    journal_title：Nature communications

    pub_type： 杂志文章,已发布勘误

    doi：10.1038/s41467-017-02128-5

    authors： Stepanauskas R,Fergusson EA,Brown J,Poulton NJ,Tupper B,Labonté JM,Becraft ED,Brown JM,Pachiadaki MG,Povilaitis T,Thompson BP,Mascena CJ,Bellows WK,Lubys A

    更新日期：2017-12-12 00:00:00

  • A pistil-expressed pectin methylesterase confers cross-incompatibility between strains of Zea mays.

    abstract：:A central problem in speciation is the origin and mechanisms of reproductive barriers that block gene flow between sympatric populations. Wind-pollinated plant species that flower in synchrony with one another rely on post-pollination interactions to maintain reproductive isolation. In some locations in Mexico, sympat...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-10259-0

    authors： Lu Y,Hokin SA,Kermicle JL,Hartwig T,Evans MMS

    更新日期：2019-05-24 00:00:00

  • Size and surface charge characterization of nanoparticles with a salt gradient.

    abstract：:Exosomes are nanometer-sized lipid vesicles present in liquid biopsies and used as biomarkers for several diseases including cancer, Alzheimer's, and central nervous system diseases. Purification and subsequent size and surface characterization are essential to exosome-based diagnostics. Sample purification is, howeve...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-15889-3

    authors： Rasmussen MK,Pedersen JN,Marie R

    更新日期：2020-05-11 00:00:00

  • Recent summer warming in northwestern Canada exceeds the Holocene thermal maximum.

    abstract：:Eastern Beringia is one of the few Western Arctic regions where full Holocene climate reconstructions are possible. However, most full Holocene reconstructions in Eastern Beringia are based either on pollen or midges, which show conflicting early Holocene summer temperature histories. This discrepancy precludes unders...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-09622-y

    authors： Porter TJ,Schoenemann SW,Davies LJ,Steig EJ,Bandara S,Froese DG

    更新日期：2019-04-09 00:00:00

  • Tuning the activities of cuprous oxide nanostructures via the oxide-metal interaction.

    abstract：:Despite tremendous importance in catalysis, the design of oxide-metal interface has been hampered by the limited understanding of the nature of interfacial sites and the oxide-metal interaction (OMI). Through construction of well-defined Cu2O/Pt, Cu2O/Ag and Cu2O/Au interfaces, we find that Cu2O nanostructures (NSs) o...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-15965-8

    authors： Huang W,Liu Q,Zhou Z,Li Y,Ling Y,Wang Y,Tu Y,Wang B,Zhou X,Deng D,Yang B,Yang Y,Liu Z,Bao X,Yang F

    更新日期：2020-05-08 00:00:00

  • Spin transport and Hanle effect in silicon nanowires using graphene tunnel barriers.

    abstract：:Spin-based devices offer non-volatile, scalable, low power and reprogrammable functionality for emerging device technologies. Here we fabricate nanoscale spintronic devices with ferromagnetic metal/single-layer graphene tunnel barriers used to generate spin accumulation and spin currents in a silicon nanowire transpor...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms8541

    authors： van 't Erve OM,Friedman AL,Li CH,Robinson JT,Connell J,Lauhon LJ,Jonker BT

    更新日期：2015-06-19 00:00:00

  • Quantum speedup in the identification of cause-effect relations.

    abstract：:The ability to identify cause-effect relations is an essential component of the scientific method. The identification of causal relations is generally accomplished through statistical trials where alternative hypotheses are tested against each other. Traditionally, such trials have been based on classical statistics. ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-09383-8

    authors： Chiribella G,Ebler D

    更新日期：2019-04-01 00:00:00

  • Few-femtosecond passage of conical intersections in the benzene cation.

    abstract：:Observing the crucial first few femtoseconds of photochemical reactions requires tools typically not available in the femtochemistry toolkit. Such dynamics are now within reach with the instruments provided by attosecond science. Here, we apply experimental and theoretical methods to assess the ultrafast nonadiabatic ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-01133-y

    authors： Galbraith MCE,Scheit S,Golubev NV,Reitsma G,Zhavoronkov N,Despré V,Lépine F,Kuleff AI,Vrakking MJJ,Kornilov O,Köppel H,Mikosch J

    更新日期：2017-10-18 00:00:00

  • Efficient and tuneable photoluminescent boehmite hybrid nanoplates lacking metal activator centres for single-phase white LEDs.

    abstract：:White light-emitting diodes (WLEDs) are candidates to revolutionize the lighting industry towards energy efficient and environmental friendly lighting and displays. The current challenges in WLEDs encompass high luminous efficiency, chromatic stability, high colour-rending index and price competitiveness. Recently, th...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms6702

    authors： Bai X,Caputo G,Hao Z,Freitas VT,Zhang J,Longo RL,Malta OL,Ferreira RA,Pinna N

    更新日期：2014-12-08 00:00:00

  • Publisher Correction: Encryption and steganography of synthetic gene circuits.

    abstract：:The original version of this Article contained an error in Fig. 4. In the lower part of the three gene circuit diagrams in panel b, the flat-headed arrow linking lambdaCI to the tetR promoter incorrectly pointed to the tetR gene body. This has now been corrected in the HTML and PDF versions of this Article. ...

    journal_title：Nature communications

    pub_type： 杂志文章,已发布勘误

    doi：10.1038/s41467-018-07844-0

    authors： Purcell O,Wang J,Siuti P,Lu TK

    更新日期：2019-01-08 00:00:00

  • Structural mechanism for gating of a eukaryotic mechanosensitive channel of small conductance.

    abstract：:Mechanosensitive ion channels transduce physical force into electrochemical signaling that underlies an array of fundamental physiological processes, including hearing, touch, proprioception, osmoregulation, and morphogenesis. The mechanosensitive channels of small conductance (MscS) constitute a remarkably diverse su...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-17538-1

    authors： Deng Z,Maksaev G,Schlegel AM,Zhang J,Rau M,Fitzpatrick JAJ,Haswell ES,Yuan P

    更新日期：2020-07-23 00:00:00

  • Mnemonic prediction errors bias hippocampal states.

    abstract：:When our experience violates our predictions, it is adaptive to upregulate encoding of novel information, while down-weighting retrieval of erroneous memory predictions to promote an updated representation of the world. We asked whether mnemonic prediction errors promote hippocampal encoding versus retrieval states, a...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-17287-1

    authors： Bein O,Duncan K,Davachi L

    更新日期：2020-07-10 00:00:00

  • Prebiotic plausibility and networks of paradox-resolving independent models.

    abstract：:The plausibility of any model in science comes from the extent of its interconnections to other models that are grounded in different premises and reasoning. Focusing research on paradoxes in those models, logic whereby they appear to generate unacceptable conclusions from seemingly indisputable premises, helps find t...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-07274-y

    authors： Benner SA

    更新日期：2018-12-12 00:00:00

  • Endocycle-related tubular cell hypertrophy and progenitor proliferation recover renal function after acute kidney injury.

    abstract：:Acute kidney injury (AKI) is considered largely reversible based on the capacity of surviving tubular cells to dedifferentiate and replace lost cells via cell division. Here we show by tracking individual tubular cells in conditional Pax8/Confetti mice that kidney function is  recovered after AKI despite substantial t...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-03753-4

    authors： Lazzeri E,Angelotti ML,Peired A,Conte C,Marschner JA,Maggi L,Mazzinghi B,Lombardi D,Melica ME,Nardi S,Ronconi E,Sisti A,Antonelli G,Becherucci F,De Chiara L,Guevara RR,Burger A,Schaefer B,Annunziato F,Anders HJ,La

    更新日期：2018-04-09 00:00:00

  • Cocaine-mediated circadian reprogramming in the striatum through dopamine D2R and PPARγ activation.

    abstract：:Substance abuse disorders are linked to alteration of circadian rhythms, although the molecular and neuronal pathways implicated have not been fully elucidated. Addictive drugs, such as cocaine, induce a rapid increase of dopamine levels in the brain. Here, we show that acute administration of cocaine triggers reprogr...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-18200-6

    authors： Brami-Cherrier K,Lewis RG,Cervantes M,Liu Y,Tognini P,Baldi P,Sassone-Corsi P,Borrelli E

    更新日期：2020-09-07 00:00:00