Abstract:
:Nivalenol is a toxic trichothecene metabolite which is produced by a number of different Fusarium species. However, the nature of its immediate biosynthetic precursor is not known. Oxidation of 7-deoxynivalenol(3 alpha,4 beta,15-trihydroxy-12,13- epoxytrichothec-9-ene-8-one) to nivalenol occurred with reagents known to react by a free radical pathway, such as hydrogen peroxide-ferrous ion-ascorbic acid or lead tetracetate, but not with electrophilic reagents requiring prior formation of the enol. These results suggest that 7-deoxynivalenol or an acetylated derivative could be the biosynthetic precursor of nivalenol.
journal_name
Mycopathologiajournal_title
Mycopathologiaauthors
Ehrlich KCdoi
10.1007/BF00707546subject
Has Abstractpub_date
1989-09-01 00:00:00pages
111-4issue
2-3eissn
0301-486Xissn
1573-0832journal_volume
107pub_type
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