A strategy for fabricating porous PdNi@Pt core-shell nanostructures and their enhanced activity and durability for the methanol electrooxidation.

Abstract:

:Three-dimensionally (3D) porous morphology of nanostructures can effectively improve their electrocatalytic activity and durability for various electrochemical reactions owing to big surface area and interconnected structure. Cyanogel, a jelly-like inorganic polymer, can be used to synthesize various three-dimensionally (3D) porous alloy nanomaterials owing to its double-metal property and particular 3D backbone. Here, 3D porous PdNi@Pt core-shell nanostructures (CSNSs) are facilely synthesized by first preparing the Pd-Ni alloy networks (Pd-Ni ANWs) core via cyanogel-reduction method followed by a galvanic displacement reaction to generate the Pt-rich shell. The as-synthesized PdNi@Pt CSNSs exhibit a much improved catalytic activity and durability for the methanol oxidation reaction (MOR) in the acidic media compared to the commercial used Pt black because of their specific structural characteristics. The facile and mild method described herein is highly attractive for the synthisis of 3D porous core-shell nanostructures.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Liu X,Xu G,Chen Y,Lu T,Tang Y,Xing W

doi

10.1038/srep07619

subject

Has Abstract

pub_date

2015-01-05 00:00:00

pages

7619

issn

2045-2322

pii

srep07619

journal_volume

5

pub_type

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