Electrochemical nonenzymatic sensor based on CoO decorated reduced graphene oxide for the simultaneous determination of carbofuran and carbaryl in fruits and vegetables.

Abstract:

:A novel nonenzymatic sensor based on cobalt (II) oxide (CoO)-decorated reduced graphene oxide (rGO) was developed for the detection of carbofuran (CBF) and carbaryl (CBR). Two well-defined and separate differential pulse voltammetric peaks for CBF and CBR were obtained with the CoO/rGO sensor in a mixed solution, making the simultaneous detection of both carbamate pesticides possible. The nonenzymatic sensor demonstrated a linear relationship over a wide concentration range of 0.2-70 μM (R=0.9996) for CBF and 0.5-200 μM (R=0.9995) for CBR. The lower detection limit of the sensor was 4.2 μg/L for CBF and 7.5 μg/L for CBR (S/N=3). The developed sensor was used to detect CBF and CBR in fruit and vegetable samples and yielded satisfactory results.

journal_name

Food Chem

journal_title

Food chemistry

authors

Wang M,Huang J,Wang M,Zhang D,Chen J

doi

10.1016/j.foodchem.2013.11.046

subject

Has Abstract

pub_date

2014-05-15 00:00:00

pages

191-7

eissn

0308-8146

issn

1873-7072

pii

S0308-8146(13)01670-1

journal_volume

151

pub_type

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