Structural feature and antioxidant activity of low molecular weight laminarin degraded by gamma irradiation.

Abstract:

:Recently, it has been reported that low molecular weight laminarin had enhanced biological activities. In this study, laminarin was degraded by gamma irradiation, and the changes in its structure and antioxidant property were investigated. Gel permeation chromatography data showed that the average molecular weight of the irradiated laminarin decreased significantly as the irradiation dose increased. The absorbance at 290nm, from UV spectra, was increased, depending on the irradiation dose and caused by the formation of carbonyl groups. From the NMR analysis, the ratio of β-1,3- to β-1,6-linkages was not changed, indicating the random scission of chains by gamma irradiation. The antioxidative activities, measured by Rancimat test, were all increased in the gamma-irradiated laminarin, depending on the absorbed dose, presumably due to the carbonyl groups formed by gamma irradiation. Therefore, gamma irradiation could be a promising method for preparing low molecular weight laminarin with enhanced biological activities.

journal_name

Food Chem

journal_title

Food chemistry

authors

Choi JI,Kim HJ,Lee JW

doi

10.1016/j.foodchem.2011.03.078

subject

Has Abstract

pub_date

2011-11-15 00:00:00

pages

520-523

issue

2

eissn

0308-8146

issn

1873-7072

pii

S0308-8146(11)00460-2

journal_volume

129

pub_type

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