Photostability of Iiovaline and its precursor 5-Ethyl-5- methylhydantoin exposed to simulated space radiations.

Abstract:

:Aqueous solutions of isovaline and its precursor molecule, 5-ethyl-5-methylhydantoin, were irradiated with ultraviolet and γ-ray photons, to evaluate their structural stability against space radiation. The degree of photolysis was measured and irradiation products were identified using chiral, reversed-phase and ion-exchange high-performance liquid chromatography. The experimental results show that the degree of photolysis of 5-ethyl-5-methylhydantoin is more significant than that of isovaline under ultraviolet light irradiation, while the results under γ-ray irradiation are the opposite. As the products of isovaline photolysis, aspartic acid, serine, glutamic acid and alanine were dominantly detected.

journal_name

Int J Mol Sci

authors

Sarker PK,Takahashi J,Kawamoto Y,Obayashi Y,Kaneko T,Kobayashi K

doi

10.3390/ijms13011006

subject

Has Abstract

pub_date

2012-01-01 00:00:00

pages

1006-17

issue

1

issn

1422-0067

pii

ijms-13-01006

journal_volume

13

pub_type

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