Degradation half-life times of PCDDs, PCDFs and PCBs for environmental fate modeling.

Abstract:

:Literature search of the knowledge on the degradation of persistent organic pollutants (POPs) in environmental compartments air, water, soil and sediment was done in purpose to find properties of POPs of interest for modeling. One degradation process, hydrolysis (chemical degradation), was omitted as negligibly slow for POPs studied. The other two, photolysis and biodegradation processes, were considered separately in purpose to develop estimation procedures. The estimates can be given as pseudo first-order rate constants kP for photolysis and kB for biodegradation. For each compartment, an overall degradation rate is k(tot) = kP + kB and lifetime t(1/2) = ln 2/k(tot). The latter values, lifetimes in each compartment, will be used as input parameters to the Baltic Sea model.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Sinkkonen S,Paasivirta J

doi

10.1016/s0045-6535(99)00337-9

subject

Has Abstract

pub_date

2000-05-01 00:00:00

pages

943-9

issue

9-11

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(99)00337-9

journal_volume

40

pub_type

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