Comparisons of the reactivity, reusability and stability of four different zero-valent iron-based nanoparticles.

Abstract:

:Our previous reports showed that nano zero-valent iron (nZVI), steel pickle liquor for the synthesis of nZVI (S-nZVI), nZVI immobilised in mesoporous silica microspheres (SiO2@FeOOH@Fe) and nano Ni/Fe bimetallic particles (Ni/Fe) have been proved to show good property for elimination of polybrominated diphenyl ethers (PBDEs). However, it is necessary to compare their reactivity, reusability and stability when applied to in situ remediation. In this study, the performances of different iron-based nanoparticles were compared through reusability, sedimentation and iron dissolution experiments. The SiO2@FeOOH@Fe and Ni/Fe nanoparticles were shown to have higher reusability and stability, as they could be reused more than seven times, and that the SiO2@FeOOH@Fe can effectively avoid leaching iron ions into the solution and causing secondary pollution in the reaction. This study may serve as a reference for PBDE remediation in the future.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Xie Y,Fang Z,Qiu X,Tsang EP,Liang B

doi

10.1016/j.chemosphere.2014.01.076

subject

Has Abstract

pub_date

2014-08-01 00:00:00

pages

433-6

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(14)00167-2

journal_volume

108

pub_type

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