The Henry's law coefficient of 2-nitrophenol over the temperature range 278-303 K.

Abstract:

:Although 2-nitrophenol has been identified as an important environmental chemical there is scarcity in the literature regarding the temperature dependence of its Henry's law coefficient, H. Here a bubble purge method was used to measure H for 2-nitrophenol over the temperature range 278-303 K. A novel approach in the data treatment allowed correction of the data for non-equilibrium partitioning in the apparatus to obtain the true equilibrium H value. The experimentally derived temperature-dependent expression for H of 2-nitrophenol is lnH (M atm(-1)) = (6290/T (K)) - 16.6. The standard enthalpy and entropy of gas-to-liquid transfer for 2-nitrophenol in aqueous solution are -52.3 +/- 8.1 kJ mol(-1) and -138 +/- 28 J mol(-1) K(-1), respectively. (Errors are 95% confidence intervals.)

journal_name

Chemosphere

journal_title

Chemosphere

authors

Müller B,Heal MR

doi

10.1016/s0045-6535(00)00592-0

subject

Has Abstract

pub_date

2001-10-01 00:00:00

pages

309-14

issue

3

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(00)00592-0

journal_volume

45

pub_type

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