Abstract:
:Although 2-nitrophenol has been identified as an important environmental chemical there is scarcity in the literature regarding the temperature dependence of its Henry's law coefficient, H. Here a bubble purge method was used to measure H for 2-nitrophenol over the temperature range 278-303 K. A novel approach in the data treatment allowed correction of the data for non-equilibrium partitioning in the apparatus to obtain the true equilibrium H value. The experimentally derived temperature-dependent expression for H of 2-nitrophenol is lnH (M atm(-1)) = (6290/T (K)) - 16.6. The standard enthalpy and entropy of gas-to-liquid transfer for 2-nitrophenol in aqueous solution are -52.3 +/- 8.1 kJ mol(-1) and -138 +/- 28 J mol(-1) K(-1), respectively. (Errors are 95% confidence intervals.)
journal_name
Chemospherejournal_title
Chemosphereauthors
Müller B,Heal MRdoi
10.1016/s0045-6535(00)00592-0subject
Has Abstractpub_date
2001-10-01 00:00:00pages
309-14issue
3eissn
0045-6535issn
1879-1298pii
S0045-6535(00)00592-0journal_volume
45pub_type
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