Determination of group parameters for organically bound chlorine, bromine and iodine in precipitation

Abstract:

:The presence of organically bound halogens in precipitation was studied by first adsorbing organics on activated carbon and then analysing the chloride, bromide and iodide formed during combustion of the carbon. A standard instrument for the group parameter AOX (adsorbable organic halogens) was used for the combustion. The halides formed were trapped in an alkaline solution and analysed by capillary zone electrophoresis. The method described enabled determination of sub-ppb concentrations of the group parameters AOCl, AOBr and AOI (adsorbable organic chlorine, bromine and iodine, respectively). Analysis of rain and snow collected at different sites in Europe showed that organochlorines were responsible for the major part of the AOX content in all samples collected. Organically bound bromine was found in sub-ppb concentrations in all of the samples, whereas organic iodine was detected in only two of the samples.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Laniewski AK,Dahlen J,Boren H,Grimvall A

doi

10.1016/s0045-6535(98)00217-3

subject

Has Abstract

pub_date

1999-02-01 00:00:00

pages

771-82

issue

4

eissn

0045-6535

issn

1879-1298

pii

S0045653598002173

journal_volume

38

pub_type

杂志文章
  • Seasonal and inter-annual variability of DNA integrity in mussels Mytilus galloprovincialis: a possible role for natural fluctuations of trace metal concentrations and oxidative biomarkers.

    abstract::The DNA strand fragmentation as analyzed by the Comet assay is a common biomarker widely used to assess the genotoxic potential of chemical pollutants in marine organisms. However, basal levels of DNA strand breaks can be influenced also by factors unrelated to chemical exposure, and a better knowledge on the natural ...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2009.09.048

    authors: Pisanelli B,Benedetti M,Fattorini D,Regoli F

    更新日期:2009-12-01 00:00:00

  • Alkylphenol oxidation with a laccase from a white-rot fungus: effects of culture induction and of ABTS used as a mediator.

    abstract::We investigated the potential of the laccase from the white-rot fungus Marasmius quercophilus to transform certain alkylphenols (p-nonylphenol, p-octylphenol and p-t-octylphenol). We tested the reactivity of this enzyme under different conditions: in liquid cultures and using the partially purified laccase with and wi...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2010.10.001

    authors: Farnet AM,Chevremont AC,Gil G,Gastaldi S,Ferre E

    更新日期:2011-01-01 00:00:00

  • Locomotor activity changes on zebrafish larvae with different 2,2',4,4'-tetrabromodiphenyl ether (PBDE-47) embryonic exposure modes.

    abstract::Polybrominated diphenyl ethers (PBDEs) are widely used flame retardants and are banned around the world as potent environmental contaminants. PBDE-47 is the most concerned PBDE with its environmental prevalence and various toxicity characteristics including neurotoxicity. In this paper, we studied larval zebrafish beh...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2013.09.010

    authors: Zhao J,Xu T,Yin DQ

    更新日期:2014-01-01 00:00:00

  • Bioactivity, toxicity and dissipation of hexaconazole enantiomers.

    abstract::In this study, the bioactivity, acute toxicity and dissipation in vegetables of the individual enantiomers of the fungicide hexaconazole had been investigated. The optical pure single enantiomers were prepared and the bioactivity of (+)-, (-)- and rac-hexaconazole was tested using four target fungi including Colletotr...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2013.09.052

    authors: Han J,Jiang J,Su H,Sun M,Wang P,Liu D,Zhou Z

    更新日期:2013-11-01 00:00:00

  • Oxidative debromination of 2,2-bis(bromomethyl)-1,3-propanediol by UV/persulfate process and corresponding formation of brominated by-products.

    abstract::This study investigated the oxidative debromination of 2,2-bis(bromomethyl)-1,3-propanediol (BBMP), a widely used brominated flame retardant, and the corresponding formation of brominated by-products by the UV/persulfate process. The debromination of BBMP by the UV/persulfate process was primarily driven by sulfate ra...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2019.04.168

    authors: Sun J,Chen Y,Xiang Y,Ling L,Fang J,Shang C

    更新日期:2019-08-01 00:00:00

  • Studying soil organic matter using 13C CP-MAS NMR: the effect of soil chemical pre-treatments on spectra quality and representativity.

    abstract::(13)C CP-MAS NMR spectroscopy is a technique that has proved to be useful in studying soil organic matter (SOM). Nevertheless, NMR spectra exhibit a weak signal and have very low resolution due to: the low natural abundance of (13)C (1.1% of C) in SOM, the generally low SOM content of soils, and the presence of parama...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2007.08.067

    authors: Salati S,Adani F,Cosentino C,Torri G

    更新日期:2008-02-01 00:00:00

  • Determination of polychlorinated dibenzo-p-dioxins and dibenzo-furans in solid residues from wood combustion by HRGC/HRMS.

    abstract::PCDD/PCDF were determined in solid samples from wood combustion. The samples included grate ashes, bottom ashes, furnace ashes as well as fly and cyclone ashes. The solid waste samples were classified into bottom and fly ash from native wood and bottom and fly ash from waste wood. For each of the four classes concentr...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/s0045-6535(99)00332-x

    authors: Wunderli S,Zennegg M,Dolezal IS,Gujer E,Moser U,Wolfensberger M,Hasler P,Noger D,Studer C,Karlaganis G

    更新日期:2000-03-01 00:00:00

  • Simulation and prediction of the thuringiensin abiotic degradation processes in aqueous solution by a radius basis function neural network model.

    abstract::The thuringiensin abiotic degradation processes in aqueous solution under different conditions, with a pH range of 5.0-9.0 and a temperature range of 10-40°C, were systematically investigated by an exponential decay model and a radius basis function (RBF) neural network model, respectively. The half-lives of thuringie...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2012.11.062

    authors: Zhou J,Xu Z,Chen S

    更新日期:2013-04-01 00:00:00

  • A rapid spectrophotometric determination of persulfate anion in ISCO.

    abstract::Due to a gradual increase in the use of persulfate as an in situ chemical oxidation (ISCO) oxidant, a simple measurement of persulfate concentration is desirable to analyze persulfate distribution at designated time intervals on/off a site. Such a distribution helps evaluate efficacy of ISCO treatment at a site. This ...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2008.08.043

    authors: Liang C,Huang CF,Mohanty N,Kurakalva RM

    更新日期:2008-11-01 00:00:00

  • Passive smoking and influenza-like illness in housewives: A perspective of gene susceptibility.

    abstract::Relation between influenza-like illness (ILI) and passive smoking remains a debate of subject. We aimed to determine an association of passive smoking with ILI risk of housewives in North China, and the modification effects of gene polymorphisms related to the metabolisms of smoking pollutants. We included 379 housewi...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2017.02.085

    authors: Wang B,Huo W,Lu Q,Li Z,Liu Y,Zhao D,Li Z

    更新日期:2017-06-01 00:00:00

  • Factors affecting ammonia volatilisation from a rice-wheat rotation system.

    abstract::Some of the major factors influencing ammonia volatilisation in a rice wheat rotation system were studied. A continuous airflow enclosure method was used to measure NH3 volatilisation in a field experiment at an agricultural college in Jiangsu Province. The five treatments comprised application rates of 0, 100, 200 or...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/s0045-6535(00)00117-x

    authors: Tian G,Cai Z,Cao J,Li X

    更新日期:2001-01-01 00:00:00

  • Adsorption and attenuation behavior of 3-nitro-1,2,4-triazol-5-one (NTO) in eleven soils.

    abstract::NTO (3-nitro-1,2,4-triazol-5-one) is one of the new explosive compounds used in insensitive munitions (IM) developed to replace traditional explosives, TNT and RDX. Data on NTO fate and transport is needed to determine its environmental behavior and potential for groundwater contamination. We conducted a series of kin...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2015.09.101

    authors: Mark N,Arthur J,Dontsova K,Brusseau M,Taylor S

    更新日期:2016-02-01 00:00:00

  • Responses of propagule germination and sexual reproduction of submerged macrophytes exposed to cadmium.

    abstract::Submerged macrophytes are considered the main primary producers in shallow lakes. Recently, they have experienced a decline due to increasing environmental impacts, e.g., excessive heavy metal loads. Compared to extensive studies on vegetative growth, reports on effects of heavy metals on propagule germination and rep...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2018.12.056

    authors: Cao Y,Liu H,Sun J,Liu Y,Jiang HS,Wang W,Li W

    更新日期:2019-03-01 00:00:00

  • The phthalate DEHP modulates the estrogen receptors α and β increasing lactotroph cell population in female pituitary glands.

    abstract::Humans are exposed to numerous endocrine disruptors on a daily basis, which may interfere with endogenous estrogens, with Di-(2-ethylhexyl) phthalate (DEHP) being one of the most employed. The anterior pituitary gland is a target of 17β-estradiol (E2) through the specific estrogen receptors (ERs) α and β, whose expres...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2020.127304

    authors: Pérez PA,Toledo J,Sosa LDV,Peinetti N,Torres AI,De Paul AL,Gutiérrez S

    更新日期:2020-11-01 00:00:00

  • Simultaneous adsorption of Cd2+ and photocatalytic degradation of tris-(2-chloroisopropyl) phosphate (TCPP) by mesoporous TiO2.

    abstract::In this work, the prepared mesoporous TiO2 was employed to eliminate the environmental risk induced by the combined pollution (tris-(2-chloroisopropyl) phosphate (TCPP) and Cd2+). The prepared material was characterized by X-ray diffraction (XRD), UV-vis diffuse reflectance spectra (UV-DRS), Raman imaging spectrometer...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2020.129238

    authors: Liu H,Yin H,Tang S,Peng H,Yu X,Lu G,Dang Z

    更新日期:2021-03-01 00:00:00

  • Heavy metal distribution between contaminated soil and Paulownia tomentosa, in a pilot-scale assisted phytoremediation study: influence of different complexing agents.

    abstract::The distribution of Cd, Cu, Pb and Zn between a contaminated soil and the tree species Paulownia tomentosa was investigated in a pilot-scale assisted phytoremediation study. The influence of the addition of EDTA, tartrate and glutamate at 1, 5 and 10mM concentrations on metal accumulation by the plant and on metal mob...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2008.04.083

    authors: Doumett S,Lamperi L,Checchini L,Azzarello E,Mugnai S,Mancuso S,Petruzzelli G,Del Bubba M

    更新日期:2008-08-01 00:00:00

  • Dioxins, DL-PCB and NDL-PCB accumulation profiles in livers from sheep and cattle reared in North-western Italy.

    abstract::Products of animal origin represent the main route of human exposure to dioxins and dioxin-like PCBs (DL-compounds). Recently, concerns have been raised about ovine products, particularly the liver, in which relatively high levels of DL-compounds have been reported. We surveyed ovine and bovine livers in areas with no...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2016.02.101

    authors: Benedetto A,Brizio P,Guaraldo P,Stella C,Cappa C,Baioni E,Spalenza V,Nebbia C,Abete MC

    更新日期:2016-06-01 00:00:00

  • Effects of dioxins and polychlorinated biphenyls (PCBs) on thyroid function in infants born in Japan--the second report from research on environmental health.

    abstract::Dioxins (PCDD + PCDF) and polychlorinated biphenyl (PCB) are potentially hazardous compounds and have structural similarity to thyroid hormones. Our research group on "Dioxins and PCB in Human Milk" was organized in 1997 and has been active for the past three years. We collected breast milk from 80 mothers living in T...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/s0045-6535(01)00050-9

    authors: Matsuura N,Uchiyama T,Tada H,Nakamura Y,Kondo N,Morita M,Fukushi M

    更新日期:2001-12-01 00:00:00

  • Anti-microbial activities of aerosolized transition metal oxide nanoparticles.

    abstract::This study used the electrospray method to create airborne droplets of metal oxide nanoparticles (NPs) and examined their anti-microbial activities, employing Escherichia coli as a model microbial species. We tested the anti-microbial activities of six metal oxide NPs (NiO, ZnO, Fe(2)O(3), Co(3)O(4), CuO, and TiO(2)) ...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2010.04.047

    authors: Wang Z,Lee YH,Wu B,Horst A,Kang Y,Tang YJ,Chen DR

    更新日期:2010-07-01 00:00:00

  • Understanding Nitrilotris(methylenephosphonic acid) reactions with ferric hydroxide.

    abstract::Phosphonate compounds are used in a wide variety of industrial and agricultural applications, and are commonly found in surface and ground waters. Adsorption to ferric hydroxide can have a significant effect on the transport and fate of phosphonate compounds in the environment. This research used density functional th...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2017.02.015

    authors: Martínez RJ,Farrell J

    更新日期:2017-05-01 00:00:00

  • Synthetic musk fragrances in trout from Danish fish farms and human milk.

    abstract::Synthetic musk compounds used in detergents and cosmetics include nitro and polycyclic musk compounds. These compounds are discharged after use via domestic wastewater and sewage treatment plants to the aquatic environment. Quantitative detection of nitro musk and polycyclic musk compounds by GC/HRMS in Danish farmed ...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2005.02.004

    authors: Duedahl-Olesen L,Cederberg T,Pedersen KH,Højgård A

    更新日期:2005-10-01 00:00:00

  • Chemical speciation of metals from marine sediments: Assessment of potential pollution risk while dredging, a case study in southern Sweden.

    abstract::Contamination associated with metals is a critical concern related to their toxicity, persistence, and bio-accumulation. Trace elements are partitioned into several chemical forms, which some are more labile during fluctuations in the environment. Studying the distribution of metals between the different chemical frac...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2020.128105

    authors: Ferrans L,Jani Y,Burlakovs J,Klavins M,Hogland W

    更新日期:2021-01-01 00:00:00

  • Changes in soil toxicity by phosphate-aided soil washing: effect of soil characteristics, chemical forms of arsenic, and cations in washing solutions.

    abstract::This study was set to investigate the changes in the toxicity of arsenic (As)-contaminated soils after washing with phosphate solutions. The soil samples collected from two locations (A: rice paddy and B: forest land) of a former smelter site were contaminated with a similar level of As. Soil washing (0.5 M phosphate ...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2014.10.038

    authors: Jho EH,Im J,Yang K,Kim YJ,Nam K

    更新日期:2015-01-01 00:00:00

  • Characterization of the accumulation of metals and organic contaminants on a novel active-passive sampling device under controlled water flow conditions.

    abstract::Recently, a new sampling device combining active and passive sampling (APS) was developed for the measurement of time-averaged concentrations of metal species and both polar and non-polar organic contaminants in water. By coupling a diffusion cell (loaded with a set of sorbents selective for different substances) with...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2019.124400

    authors: Amato ED,Nguyen DT,Subotic D,Hereijgers J,Breugelmans T,Weyn M,Dardenne F,Bervoets L,Covaci A,Town RM,Blust R

    更新日期:2019-12-01 00:00:00

  • Identification of oxidative coupling products of xylenols arising from laboratory-scale phytoremediation.

    abstract::Oxidative coupling reactions take place during the passage of xylenols through a laboratory-scale helophyte-based constructed wetland system. Typical coupling product groups including tetramethyl-[1,1'-biphenyl] diols and tetramethyl diphenylether monools as stable organic intermediates could be identified by a combin...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2014.06.004

    authors: Poerschmann J,Schultze-Nobre L,Ebert RU,Górecki T

    更新日期:2015-01-01 00:00:00

  • Removal of methyl parathion from water by electrochemically generated Fenton's reagent.

    abstract::The electro-Fenton process was used to assess the degradation of methyl parathion (MP) in aqueous solutions. This oxidation process allows the production of hydroxyls radicals which react on the organic compounds, leading to their mineralization. Degradation experiments were performed either in perchloric, sulphuric, ...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2006.06.033

    authors: Diagne M,Oturan N,Oturan MA

    更新日期:2007-01-01 00:00:00

  • Effects of light irradiation on the complexes of cadmium and humic acids: The role of thiol groups.

    abstract::In natural environments, humic substances (HS) play a key role in the control of Cd stability by forming Cd-HS complexes. In this study, we investigated the influence of the photo-irradiation on the Cd levels remaining in Leonardite humic acid (HA) standard solution after chemical precipitation. The kinetic experiment...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2019.03.029

    authors: Jia Y,Zhao T,Zhao N,Wei H,Zhang W,Qiu R

    更新日期:2019-06-01 00:00:00

  • Cu (II) removal using electrospun dual-responsive polyethersulfone-poly (dimethyl amino) ethyl methacrylate (PES-PDMAEMA) blend nanofibers.

    abstract::A novel electrospun dual-responsive polyethersulfone-poly(dimethyl amino) ethyl methacrylate nanofibrous adsorbent was fabricated via electrospinning for the removal of Cu (II) from aqueous solution. Morphological, chemical, and dual-responsiveness of the composite nanofibrous adsorbent were characterized using scanni...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2019.125287

    authors: Bornillo KAS,Kim S,Choi H

    更新日期:2020-03-01 00:00:00

  • Polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) in the sediments of an Italian drinking water reservoir.

    abstract::The concentration of 9 polychlorinated biphenyls (PCB 28, 52, 101, 151, 153, 170, 180, 183 and 194) and of 6 micropollutants commonly classified as organochlorine pesticides, or OCPs (alpha-HCH, beta-HCH, gamma-HCH, p,p'-DDT, p,p'-DDE and p,p'-DDD), was determined in 22 sediment samples of lake Simbirizzi, an artifici...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/s0045-6535(97)10035-2

    authors: Kalajzic T,Bianchi M,Muntau H,Kettrup A

    更新日期:1998-03-01 00:00:00

  • Influences of hexafluoropropylene oxide (HFPO) homologues on soil microbial communities.

    abstract::Hexafluoropropylene oxide (HFPO) homologues, as emerging perfluoroalkyl substances (PFASs) to replace legacy PFASs, have wide applications in the organofluorine industry and have been detected in the global environment. However, it is still unclear what effect HFPO homologues will exert on microbial abundance, communi...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2020.127504

    authors: Ke Y,Tong T,Chen J,Huang J,Xie S

    更新日期:2020-11-01 00:00:00