Abstract:
:The presence of organically bound halogens in precipitation was studied by first adsorbing organics on activated carbon and then analysing the chloride, bromide and iodide formed during combustion of the carbon. A standard instrument for the group parameter AOX (adsorbable organic halogens) was used for the combustion. The halides formed were trapped in an alkaline solution and analysed by capillary zone electrophoresis. The method described enabled determination of sub-ppb concentrations of the group parameters AOCl, AOBr and AOI (adsorbable organic chlorine, bromine and iodine, respectively). Analysis of rain and snow collected at different sites in Europe showed that organochlorines were responsible for the major part of the AOX content in all samples collected. Organically bound bromine was found in sub-ppb concentrations in all of the samples, whereas organic iodine was detected in only two of the samples.
journal_name
Chemospherejournal_title
Chemosphereauthors
Laniewski AK,Dahlen J,Boren H,Grimvall Adoi
10.1016/s0045-6535(98)00217-3subject
Has Abstractpub_date
1999-02-01 00:00:00pages
771-82issue
4eissn
0045-6535issn
1879-1298pii
S0045653598002173journal_volume
38pub_type
杂志文章相关文献
CHEMOSPHERE文献大全abstract::The DNA strand fragmentation as analyzed by the Comet assay is a common biomarker widely used to assess the genotoxic potential of chemical pollutants in marine organisms. However, basal levels of DNA strand breaks can be influenced also by factors unrelated to chemical exposure, and a better knowledge on the natural ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2009.09.048
更新日期:2009-12-01 00:00:00
abstract::We investigated the potential of the laccase from the white-rot fungus Marasmius quercophilus to transform certain alkylphenols (p-nonylphenol, p-octylphenol and p-t-octylphenol). We tested the reactivity of this enzyme under different conditions: in liquid cultures and using the partially purified laccase with and wi...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2010.10.001
更新日期:2011-01-01 00:00:00
abstract::Polybrominated diphenyl ethers (PBDEs) are widely used flame retardants and are banned around the world as potent environmental contaminants. PBDE-47 is the most concerned PBDE with its environmental prevalence and various toxicity characteristics including neurotoxicity. In this paper, we studied larval zebrafish beh...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2013.09.010
更新日期:2014-01-01 00:00:00
abstract::In this study, the bioactivity, acute toxicity and dissipation in vegetables of the individual enantiomers of the fungicide hexaconazole had been investigated. The optical pure single enantiomers were prepared and the bioactivity of (+)-, (-)- and rac-hexaconazole was tested using four target fungi including Colletotr...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2013.09.052
更新日期:2013-11-01 00:00:00
abstract::This study investigated the oxidative debromination of 2,2-bis(bromomethyl)-1,3-propanediol (BBMP), a widely used brominated flame retardant, and the corresponding formation of brominated by-products by the UV/persulfate process. The debromination of BBMP by the UV/persulfate process was primarily driven by sulfate ra...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.04.168
更新日期:2019-08-01 00:00:00
abstract::(13)C CP-MAS NMR spectroscopy is a technique that has proved to be useful in studying soil organic matter (SOM). Nevertheless, NMR spectra exhibit a weak signal and have very low resolution due to: the low natural abundance of (13)C (1.1% of C) in SOM, the generally low SOM content of soils, and the presence of parama...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2007.08.067
更新日期:2008-02-01 00:00:00
abstract::PCDD/PCDF were determined in solid samples from wood combustion. The samples included grate ashes, bottom ashes, furnace ashes as well as fly and cyclone ashes. The solid waste samples were classified into bottom and fly ash from native wood and bottom and fly ash from waste wood. For each of the four classes concentr...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(99)00332-x
更新日期:2000-03-01 00:00:00
abstract::The thuringiensin abiotic degradation processes in aqueous solution under different conditions, with a pH range of 5.0-9.0 and a temperature range of 10-40°C, were systematically investigated by an exponential decay model and a radius basis function (RBF) neural network model, respectively. The half-lives of thuringie...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2012.11.062
更新日期:2013-04-01 00:00:00
abstract::Due to a gradual increase in the use of persulfate as an in situ chemical oxidation (ISCO) oxidant, a simple measurement of persulfate concentration is desirable to analyze persulfate distribution at designated time intervals on/off a site. Such a distribution helps evaluate efficacy of ISCO treatment at a site. This ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2008.08.043
更新日期:2008-11-01 00:00:00
abstract::Relation between influenza-like illness (ILI) and passive smoking remains a debate of subject. We aimed to determine an association of passive smoking with ILI risk of housewives in North China, and the modification effects of gene polymorphisms related to the metabolisms of smoking pollutants. We included 379 housewi...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.02.085
更新日期:2017-06-01 00:00:00
abstract::Some of the major factors influencing ammonia volatilisation in a rice wheat rotation system were studied. A continuous airflow enclosure method was used to measure NH3 volatilisation in a field experiment at an agricultural college in Jiangsu Province. The five treatments comprised application rates of 0, 100, 200 or...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(00)00117-x
更新日期:2001-01-01 00:00:00
abstract::NTO (3-nitro-1,2,4-triazol-5-one) is one of the new explosive compounds used in insensitive munitions (IM) developed to replace traditional explosives, TNT and RDX. Data on NTO fate and transport is needed to determine its environmental behavior and potential for groundwater contamination. We conducted a series of kin...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2015.09.101
更新日期:2016-02-01 00:00:00
abstract::Submerged macrophytes are considered the main primary producers in shallow lakes. Recently, they have experienced a decline due to increasing environmental impacts, e.g., excessive heavy metal loads. Compared to extensive studies on vegetative growth, reports on effects of heavy metals on propagule germination and rep...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.12.056
更新日期:2019-03-01 00:00:00
abstract::Humans are exposed to numerous endocrine disruptors on a daily basis, which may interfere with endogenous estrogens, with Di-(2-ethylhexyl) phthalate (DEHP) being one of the most employed. The anterior pituitary gland is a target of 17β-estradiol (E2) through the specific estrogen receptors (ERs) α and β, whose expres...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.127304
更新日期:2020-11-01 00:00:00
abstract::In this work, the prepared mesoporous TiO2 was employed to eliminate the environmental risk induced by the combined pollution (tris-(2-chloroisopropyl) phosphate (TCPP) and Cd2+). The prepared material was characterized by X-ray diffraction (XRD), UV-vis diffuse reflectance spectra (UV-DRS), Raman imaging spectrometer...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.129238
更新日期:2021-03-01 00:00:00
abstract::The distribution of Cd, Cu, Pb and Zn between a contaminated soil and the tree species Paulownia tomentosa was investigated in a pilot-scale assisted phytoremediation study. The influence of the addition of EDTA, tartrate and glutamate at 1, 5 and 10mM concentrations on metal accumulation by the plant and on metal mob...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2008.04.083
更新日期:2008-08-01 00:00:00
abstract::Products of animal origin represent the main route of human exposure to dioxins and dioxin-like PCBs (DL-compounds). Recently, concerns have been raised about ovine products, particularly the liver, in which relatively high levels of DL-compounds have been reported. We surveyed ovine and bovine livers in areas with no...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.02.101
更新日期:2016-06-01 00:00:00
abstract::Dioxins (PCDD + PCDF) and polychlorinated biphenyl (PCB) are potentially hazardous compounds and have structural similarity to thyroid hormones. Our research group on "Dioxins and PCB in Human Milk" was organized in 1997 and has been active for the past three years. We collected breast milk from 80 mothers living in T...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(01)00050-9
更新日期:2001-12-01 00:00:00
abstract::This study used the electrospray method to create airborne droplets of metal oxide nanoparticles (NPs) and examined their anti-microbial activities, employing Escherichia coli as a model microbial species. We tested the anti-microbial activities of six metal oxide NPs (NiO, ZnO, Fe(2)O(3), Co(3)O(4), CuO, and TiO(2)) ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2010.04.047
更新日期:2010-07-01 00:00:00
abstract::Phosphonate compounds are used in a wide variety of industrial and agricultural applications, and are commonly found in surface and ground waters. Adsorption to ferric hydroxide can have a significant effect on the transport and fate of phosphonate compounds in the environment. This research used density functional th...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.02.015
更新日期:2017-05-01 00:00:00
abstract::Synthetic musk compounds used in detergents and cosmetics include nitro and polycyclic musk compounds. These compounds are discharged after use via domestic wastewater and sewage treatment plants to the aquatic environment. Quantitative detection of nitro musk and polycyclic musk compounds by GC/HRMS in Danish farmed ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2005.02.004
更新日期:2005-10-01 00:00:00
abstract::Contamination associated with metals is a critical concern related to their toxicity, persistence, and bio-accumulation. Trace elements are partitioned into several chemical forms, which some are more labile during fluctuations in the environment. Studying the distribution of metals between the different chemical frac...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.128105
更新日期:2021-01-01 00:00:00
abstract::This study was set to investigate the changes in the toxicity of arsenic (As)-contaminated soils after washing with phosphate solutions. The soil samples collected from two locations (A: rice paddy and B: forest land) of a former smelter site were contaminated with a similar level of As. Soil washing (0.5 M phosphate ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2014.10.038
更新日期:2015-01-01 00:00:00
abstract::Recently, a new sampling device combining active and passive sampling (APS) was developed for the measurement of time-averaged concentrations of metal species and both polar and non-polar organic contaminants in water. By coupling a diffusion cell (loaded with a set of sorbents selective for different substances) with...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.124400
更新日期:2019-12-01 00:00:00
abstract::Oxidative coupling reactions take place during the passage of xylenols through a laboratory-scale helophyte-based constructed wetland system. Typical coupling product groups including tetramethyl-[1,1'-biphenyl] diols and tetramethyl diphenylether monools as stable organic intermediates could be identified by a combin...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2014.06.004
更新日期:2015-01-01 00:00:00
abstract::The electro-Fenton process was used to assess the degradation of methyl parathion (MP) in aqueous solutions. This oxidation process allows the production of hydroxyls radicals which react on the organic compounds, leading to their mineralization. Degradation experiments were performed either in perchloric, sulphuric, ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2006.06.033
更新日期:2007-01-01 00:00:00
abstract::In natural environments, humic substances (HS) play a key role in the control of Cd stability by forming Cd-HS complexes. In this study, we investigated the influence of the photo-irradiation on the Cd levels remaining in Leonardite humic acid (HA) standard solution after chemical precipitation. The kinetic experiment...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.03.029
更新日期:2019-06-01 00:00:00
abstract::A novel electrospun dual-responsive polyethersulfone-poly(dimethyl amino) ethyl methacrylate nanofibrous adsorbent was fabricated via electrospinning for the removal of Cu (II) from aqueous solution. Morphological, chemical, and dual-responsiveness of the composite nanofibrous adsorbent were characterized using scanni...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.125287
更新日期:2020-03-01 00:00:00
abstract::The concentration of 9 polychlorinated biphenyls (PCB 28, 52, 101, 151, 153, 170, 180, 183 and 194) and of 6 micropollutants commonly classified as organochlorine pesticides, or OCPs (alpha-HCH, beta-HCH, gamma-HCH, p,p'-DDT, p,p'-DDE and p,p'-DDD), was determined in 22 sediment samples of lake Simbirizzi, an artifici...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(97)10035-2
更新日期:1998-03-01 00:00:00
abstract::Hexafluoropropylene oxide (HFPO) homologues, as emerging perfluoroalkyl substances (PFASs) to replace legacy PFASs, have wide applications in the organofluorine industry and have been detected in the global environment. However, it is still unclear what effect HFPO homologues will exert on microbial abundance, communi...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.127504
更新日期:2020-11-01 00:00:00