Abstract:
:A water surface sampler (WSS) was employed in combination with greased surface deposition plates (GSDPs) to measure the particulate dry deposition and gas exchange of polychlorinated biphenyls (PCBs) in Chicago, IL. Vapor phase PCB fluxes were calculated by subtracting the particulate fluxes obtained from GSDPs from total (particulate+gas) fluxes obtained from the WSS. Vapor phase PCB fluxes were divided by ambient air concentrations measured with a high volume sampler to calculate overall gas phase PCB mass transfer coefficients (K(G)). The calculated average PCB MTC was 0.54+/-0.47 cm s(-1). This experimentally determined average gas phase overall mass transfer coefficient, K(G), agreed well with the ones reported from studies using similar techniques and agreed well with modeled values obtained using MTC correlations developed for the WSS.
journal_name
Chemospherejournal_title
Chemosphereauthors
Tasdemir Y,Odabasi M,Holsen TMdoi
10.1016/j.chemosphere.2006.08.009subject
Has Abstractpub_date
2007-01-01 00:00:00pages
1554-60issue
8eissn
0045-6535issn
1879-1298pii
S0045-6535(06)01094-0journal_volume
66pub_type
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