Abstract：
:The use of soluble and highly oxidizing Ag(III) in the form of the tetrahydroxoargentate ion Ag(OH)4- is reported for the oxidation of surrogate organic recalcitrant dyes (i.e., rhodamine 6G (Rh6G) and fluorescein (Fl)). The possible use of Ag(OH)4- for the treatment of these and other refractory compounds is assessed. Such dyes were selected due to their common occurrence, stability, refractory nature, the relatively high toxicity of Rh6G, and their structural similarity to Fl. Several reaction intermediates/products were identified. The results showed that the highly oxidizing tetrahydroxoargentate anion was capable of degrading these recalcitrant dyes. Furthermore, the final degradation products do not represent a higher environmental risk than the original surrogates themselves. In addition, the partial mineralization of the dyes was proven.
journal_name
Chemospherejournal_title
Chemosphereauthors
Zamora-Garcia IR,Alatorre-Ordaz A,Ibanez JG,Torres-Elguera JC,Wrobel K,Gutierrez-Granados Sdoi
10.1016/j.chemosphere.2017.10.041subject
Has Abstractpub_date
2018-01-01 00:00:00pages
400-407eissn
0045-6535issn
1879-1298pii
S0045-6535(17)31620-Xjournal_volume
191pub_type
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