Abstract:
:Bromination of ethynylestradiol (EE2) was studied using fluorescence and conventional and stopped-flow absorbance spectroscopy. EE2 transformations in the presence of bromine were determined to proceed through sequential reactions. The first step is very rapid and results in the formation of a brominated cyclohexadienone that is susceptible to reduction but in oxidative conditions it undergoes a transformation into monobromo-EE2 in a first-order OH- -accelerated reaction. The transformation from monobromo-EE2 to dibromo-EE2 follows a similar mechanism. The rates of reactions of bromine-substituted EE2 species are orders of magnitude lower than that of the parent compound indicating that these species can persist in conditions typical for water treatment operations.
journal_name
Chemospherejournal_title
Chemosphereauthors
Lu J,Korshin GVdoi
10.1016/j.chemosphere.2008.02.055subject
Has Abstractpub_date
2008-06-01 00:00:00pages
504-8issue
3eissn
0045-6535issn
1879-1298pii
S0045-6535(08)00273-7journal_volume
72pub_type
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