Abstract:
:The formation and control of haloacetamides (HAcAms) in drinking water have raised high attention due to their high genotoxicity and cytotoxicity, especially the most cytotoxic one, diiodoacetamide (DIAcAm). In this study, the degradation of DIAcAm by UV/chlorination was investigated in terms of degradation kinetics, efficiency, influencing factors, oxidation products and toxicity evaluation. Results revealed that the degradation of DIAcAm by UV/chlorine process followed pseudo-first-order kinetics, and the rate constant between DIAcAm and OH radicals was determined as 2.8 × 109 M-1 s-1. The contribution of Cl to DIAcAm degradation by UV/chlorine oxidation was negligible. Increasing chlorine dosage and decreasing pH significantly promoted the DIAcAm degradation during UV/chlorine oxidation, but the presence of bicarbonate (HCO3-) and natural organic matter (NOM) inhibited it. The mass balance analysis of iodine species was also evaluated during UV/chlorine oxidation of DIAcAm. In this process, with DIAcAm decreasing from 16.0 to 0.8 μM-I in 20 min, IO3-, I- and HOI/I2 increased from 0 to 6.3, 6.1 and 0.5 μM-I, respectively. The increase of CHO cell viability during DIAcAm degradation indicated that the toxicity of DIAcAm could be decreased by chlorination, UV irradiation and UV/chlorine oxidation treatments, in which UV/chlorine oxidation was more effective on toxicity reduction than chlorination and UV irradiation alone.
journal_name
Chemospherejournal_title
Chemosphereauthors
Liu Z,Lin YL,Xu B,Hu CY,Zhang TY,Cao TC,Pan Y,Gao NYdoi
10.1016/j.chemosphere.2019.124761subject
Has Abstractpub_date
2020-02-01 00:00:00pages
124761eissn
0045-6535issn
1879-1298pii
S0045-6535(19)31998-8journal_volume
240pub_type
杂志文章相关文献
CHEMOSPHERE文献大全abstract::Passive sampling is increasingly applied for monitoring neutral hydrophobic compounds (HOC) in various environmental media like water, sediment, air and also soft biota tissue. Passive samplers for HOC are often constructed from permeable polymers like silicone and polyethylene (PE), while also SPMD are often applied....
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.01.164
更新日期:2019-05-01 00:00:00
abstract::This study focused on an estuarine wildlife species exhibiting high site fidelity and ubiquitous distribution in coastal environments along the Atlantic and Gulf coasts of the United States to monitor per- and polyfluoroalkyl substances (PFAS). A total of 75 diamondback terrapin (Malaclemys terrapin) plasma samples we...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.10.023
更新日期:2019-01-01 00:00:00
abstract::Bicarbonate anion is an efficient activator for hydrogen peroxide to generate many active oxygen species including peroxymonocarbonate (HCO(4)(-)), superoxide ion (O(2)(-)) and singlet oxygen ((1)O(2)). This study aims to understand the oxidative degradation of organic pollutants including methyl blue, methyl orange, ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2010.11.066
更新日期:2011-02-01 00:00:00
abstract::Four different metal-contaminated calcareous soil types, Carbonati-Perudic Cambosols (CPC), Fe-accumuli-Stagnic Anthrosols (FSA), Ochri-Aquic Cambosols (OAC) and Calci-Orthic Aridosols (COA), were investigated. The acid buffering capacity and metal-releasing behaviors of the soils were explored using an acid extractio...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.127045
更新日期:2020-10-01 00:00:00
abstract::A global chemical transport model (MOZART-2; model of ozone and related tracers, version 2) was used to assess physical and chemical processes that control the budget of tropospheric carbon monoxide (CO) in North China. Satellite observations of CO from the measurements of pollution in the troposphere (MOPITT) instrum...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2006.09.055
更新日期:2007-01-01 00:00:00
abstract::Environmental concentrations of toxic substances are not necessarily constant but fluctuate over time. Periods of intense exposure might be followed by episodes with a relatively low or no exposure, in principle allowing exposed organisms to recover from toxic injury. The growth reproduction assay with the limnic vasc...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2006.10.018
更新日期:2007-02-01 00:00:00
abstract::One lab-scale biofilter that simultaneously removes Fe, Mn and ammonia from 4 °C groundwater was established to investigate the nitrogen conversion process. The results showed that 333 days were needed to achieve the required standards for Fe, Mn and ammonia under a filtration rate of 3 m/h. Effluent nitrite concentra...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.01.143
更新日期:2019-05-01 00:00:00
abstract::Tebuconazole is a triazole compound used agriculturally to treat plant pathogenic fungi. However, whether pubertal exposure to tebuconazole affects Leydig cell development remains unknown. Here, we exposed male Sprague-Dawley rats at 35 days of age to 0, 25, 50, or 100 mg kg-1 day-1 tebuconazole for 21 days. Tebuconaz...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.05.122
更新日期:2019-09-01 00:00:00
abstract::We present STREAM-EU (Spatially and Temporally Resolved Exposure Assessment Model for EUropean basins), a novel dynamic mass balance model for predicting the environmental fate of organic contaminants in river basins. STREAM-EU goes beyond the current state-of-the-science in that it can simulate spatially and temporal...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2015.09.051
更新日期:2016-02-01 00:00:00
abstract::Phytoremediation is a promising and cost-effective strategy to manage heavy metal polluted sites. In this experiment, we compared simultaneously phytoextraction and phytostabilisation techniques on a Cd and Zn contaminated soil, through monitoring of plant accumulation and leaching. Lolium perenne plants were cultivat...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2011.07.034
更新日期:2011-11-01 00:00:00
abstract::Oil sands mining in the Athabasca region of northern Alberta results in the production of large volumes of oil sands process-affected water (OSPW). We have evaluated the effects of OSPW, the acid extractable organic (AEO) fraction of OSPW, and individual naphthenic acids (NAs) on the germination and development of the...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2013.04.101
更新日期:2013-09-01 00:00:00
abstract::Batch type and column experiments were used to study competitive adsorption-desorption and transport for Cd, Cu, Ni and Zn in a mine soil, both un-amended and amended with mussel shell. Batch type experiments showed that adsorption was affected by the added concentration of the metals, generally following the sequence...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2013.12.097
更新日期:2014-07-01 00:00:00
abstract::Lead concentration is increasing rapidly in the environment due to increased use of its sources by human society. Alarming concentrations of the metal have been reported in dust of densely populated urban areas and, water and land of various areas near the industrial waste disposals. Plants absorb lead and accumulatio...
journal_title:Chemosphere
pub_type: 杂志文章,评审
doi:10.1016/s0045-6535(97)00087-8
更新日期:1997-06-01 00:00:00
abstract::The present study was performed on Shorea robusta Gaertn., Acacia auriculiformis Benth., Eucalyptus globulus Labill., Azadirachta indica A. Juss in two tropical forests [including one (Barjora), situated adjacent to heavy pollution sources and the other, as control, Ballavpur Wildlife Sanctuary (BWLS)] of West Bengal,...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.124522
更新日期:2019-12-01 00:00:00
abstract::The former Pb-Zn mining town of Kabwe in central Zambia is ranked amongst the worst polluted areas both in Africa and in the world. The fine dust particles from the ISF and Waelz slags deposited in Kabwe represent a health risk for the local population. Here, we combined a detailed multi-method mineralogical investiga...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.127642
更新日期:2020-12-01 00:00:00
abstract::Dispersed swine wastewater has increasingly aggravated water pollution in China. Anaerobically digested dispersed swine wastewater was targeted and treated by a pilot-scale zoning tidal flow constructed wetland (TFCW) with a bottom wastewater saturation layer. The long-term application of in-situ biological regenerati...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.11.036
更新日期:2019-02-01 00:00:00
abstract::Tris (2-butoxyethyl) phosphate (TBOEP), as one of the most widely used organophosphate flame retardants (OPFRs), is applied in nearly all manufactured items and materials. It has been reported that TBOEP could cause developmental impairments and disrupt the endocrine regulation of fish growth during acute toxic experi...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.08.102
更新日期:2018-12-01 00:00:00
abstract::Blood of adult and juvenile black and turkey vultures in the Savannah River Site of South Carolina, USA was analyzed for the presence of 2,3,7,8-chlorine substituted polychlorinated dibenzo-p-dioxins (2,3,7,8-PCDDs), dibenzofurans (2,3,7,8-PCDFs), -dioxin-like and -di-ortho polychlorinated biphenyls. Concentration ran...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/S0045-6535(03)00304-7
更新日期:2003-10-01 00:00:00
abstract::The Fenton process, one of several advanced oxidation processes, describes the reaction of Fe(II) with hydrogen peroxide. Fe(II) is oxidized to Fe(III) that reacts with hydrogen peroxide to Fe(II) and again initiates the Fenton reaction. In the course of the reactions reactive species, e.g. hydroxyl radicals, are form...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.05.039
更新日期:2017-09-01 00:00:00
abstract::Atrazine (AZ) is an environmental endocrine disrupting chemical which can affect the development of amphibians. In our past studies, we demonstrated that chronical exposure to 100 μg/L AZ can cause abnormalities in development and related genes expression of gonads in developing male Xenopus laevis (X. laevis) tadpole...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.02.140
更新日期:2018-06-01 00:00:00
abstract::The content of phthalate esters (PAEs) was investigated in 36 vegetable fields with plastic film mulching in Shandong Peninsula, East China. Soils at depths of 0-10 cm, 10-20 cm, and 20-40 cm were collected, and 16 PAEs were analyzed by gas chromatography-mass spectrometry. PAEs were detected in all the analyzed sampl...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.08.068
更新日期:2016-12-01 00:00:00
abstract::The organic toxicants present in the effluent of the main sewer of the city of Zagreb, Croatia were isolated and identified through the use of effects-directed characterisation techniques. At the time of investigation, the wastewater effluent received no treatment and was comprised of a mixture of effluent from domest...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2006.09.021
更新日期:2007-02-01 00:00:00
abstract::Time of flight secondary ion mass spectroscopy has been used to study the metal distribution at the soil/root interface of tree roots extracted from smelter-impacted soils. The results, augmented by scanning electron microscopy, show that the technique is capable of resolving metal distributions at the cellular level....
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2003.07.010
更新日期:2004-02-01 00:00:00
abstract::Brominated flame retardants (BFRs) are the compounds used in the industry in order to decrease flammability of various everyday products. The use of BFRs leads to migration of these substances into the environment, which results in the exposure of humans to their action. Although BFRs are widespread in human surroundi...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.127705
更新日期:2020-12-01 00:00:00
abstract::Microbially enhanced availability and phytoextraction is a promising technique for phytoremediation of lead (Pb). In this study, Pb resistant strains were isolated and investigated for potential effects on plant growth and Pb phytoextraction. Incubation experiments were carried for inoculated and un-inoculated soil co...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.04.093
更新日期:2019-07-01 00:00:00
abstract::The demand for high quality recycled polymers in the European plastic industry is on the increase, likely due to the EU's Plastic Strategy intended to implement the circular economy model in this sector. The problem is that there is not enough recycled plastic in the market. In terms of volume, post-consumer plastic w...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.126373
更新日期:2020-07-01 00:00:00
abstract::Enols are an important group of photochemical precursors of atmospheric carbonyl compounds. However, the transformation mechanism is not fully understood. In this study, the photo-induced transformation of a typical enol, allyl alcohol, to carbonyl compounds on TiO2 (P25) and aluminum reduced TiO2 (P25, rutile and ana...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.05.219
更新日期:2019-10-01 00:00:00
abstract::A series of CX-TiO2(Carbon Xerogel- TiO2) composites with a hierarchical porous structure were obtained through the sol-gel method followed by drying and carbonization, and have been applied to treating solubilizing wastewater containing a high concentration of phenanthrene (PHE). The characterizations demonstrated th...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.127588
更新日期:2020-12-01 00:00:00
abstract::Ground discarded tires adsorb naphthalene, toluene, and mercury ions (Hg2+) from aqueous solutions. Their sorption properties and kinetics were determined by batch equilibration techniques at 20 degrees C. The isotherms were linear for naphthalene and toluene and their sorption coefficients were about 1340 and 255 (ml...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(00)00016-3
更新日期:2000-10-01 00:00:00
abstract::The speciation of Al3+ in aqueous solutions containing organic and inorganic ligands important from a biological (citrate (Cit3-), gluconate (Gluc-), lactate (Lac-), silicate (H2SiO42-), carbonate (CO32-), fluoride (F-)) and industrial (Gantrez®; polymethyl-vinyl-ether-co-maleic acids; GTZ S95 and GTZ AN169) point of ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.08.015
更新日期:2017-11-01 00:00:00