A simple method for removing chelated copper from wastewaters: Ca(OH)(2)-based replacement-precipitation.

Abstract:

:A simple Ca(OH)(2)-based replacement-precipitation process was applied to the removal of EDTA-chelated copper from wastewaters. The effect of initial pH of the solution, molar ratio of Ca(2+) to Cu(II), the presence of CO(2) on the removal efficiency was investigated. The experimental results showed that the Ca(OH)(2)-based replacement-precipitation process could efficiently remove the chelated copper from wastewaters. When 12 < or = pH < or = 13 and molar ratio of Ca(2+) to > or = Cu(II)2, the removal efficiency could reach 99% above, also being close to the theoretically simulated results. The presence of CO(2) in the air would exert negative effect on the removal efficiency, but the side effect could be effectively eliminated by the addition of flocculation agent polyacrylamide. Compared with Fe(2+)-based replacement-precipitation technique applied in industrial practice, the method possesses the advantages of less sludge, lower cost, higher removal efficiency and higher controllability.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Jiang S,Fu F,Qu J,Xiong Y

doi

10.1016/j.chemosphere.2008.06.010

subject

Has Abstract

pub_date

2008-10-01 00:00:00

pages

785-90

issue

5

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(08)00762-5

journal_volume

73

pub_type

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