Abstract:
:The chemical composition of the odors typical of fires has recently been deciphered. Basically the constituents are mixtures of acetophenone, benzyl alcohol, hydroxylated derivatives of benzaldehyde, methoxylated and/or alkylated phenols and naphthalene. This finding makes it possible to develop objective, practical analytic measurement methods for the burnt smell as a contribution to improving fire damage assessment and remediation monitoring. With the aid of an artificially produced burnt smell and a panel of testers the odor detection threshold of a test mixture was determined olfactometrically to 2 μg m⁻³. Using a defined burnt-smell atmosphere in a test chamber, analytical methods with active sampling, the adsorbents XAD 7 and TENAX TA, and GC/MS measurement were then optimized and tested with a view to being able to carry out sensitive quantitative measurement of burnt smells. A further practical method with particular application to the qualitative characterization of this odor is based on the use of a new SPME (solid-phase microextraction) field sampler with DVB/CAR/PDMS (divinylbenzene/Carboxen™/polydimethylsiloxane) fibers.
journal_name
Chemospherejournal_title
Chemosphereauthors
Heitmann K,Wichmann H,Bahadir M,Gunschera J,Schulz N,Salthammer Tdoi
10.1016/j.chemosphere.2010.09.065subject
Has Abstractpub_date
2011-01-01 00:00:00pages
237-43issue
2eissn
0045-6535issn
1879-1298pii
S0045-6535(10)01092-1journal_volume
82pub_type
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