Passive samplers versus surfactant extraction for the evaluation of PAH availability in sediments with variable levels of contamination.

Abstract:

:The purpose of this study was to test the efficiency of passive solid samplers, polyoxymethylene (POM) strips and polydimethylsiloxane (PDMS) silicon tubing, to predict the bioavailability of native PAHs in contaminated sediments. Results were compared with worm bioaccumulation data and solid/liquid extraction using the surfactant Brij((R)) 700 (B700). The two passive samplers were found to act differently. The PDMS sampler overestimated the availability of PAHs in all studied sediments. The POM method provided results in accordance with those obtained with the B700 extraction. However, POM and B700 methods underestimated PAH availability in low contaminated sediments where biological factors (digestible organic matter) become important. Bioavailability of total PAHs was correctly predicted by POM and B700 in highly contaminated aluminum smelter sediments. A closer examination of individual PAH results indicated that both techniques overestimated the availability of large molecules with logK(ow)>6 suggesting a biological mechanism limiting uptake of larger PAHs which seems to be related to the molecular size of compounds.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Barthe M,Pelletier E,Breedveld GD,Cornelissen G

doi

10.1016/j.chemosphere.2007.12.015

subject

Has Abstract

pub_date

2008-04-01 00:00:00

pages

1486-93

issue

8

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(07)01538-X

journal_volume

71

pub_type

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