Abstract：
:A combined treatment for the degradation of the chlorophenoxy herbicides 2,4-D and MCPA in water by means of Fenton and biological oxidation has been studied. The chemical oxidation step was necessary to achieve an efficient removal of these pollutants due to their toxicity and low biodegradability. Aqueous herbicide solutions (180mgL(-1)) were subjected to Fenton oxidation upon different H2O2 doses (from the theoretical stoichiometric amount referred to initial COD to 20% of this value). The toxicity and biodegradability tests of the Fenton effluents suggested that the ones resulting upon treatment with 80% and 60% of stoichiometric H2O2 were the optimal for subsequent biological treatment dealing with 2,4-D and MCPA, respectively. These effluents were treated in a sequencing batch reactor achieving nearly 90% conversion of organic matter measured as COD.
journal_name
Chemospherejournal_title
Chemosphereauthors
Sanchis S,Polo AM,Tobajas M,Rodriguez JJ,Mohedano AFdoi
10.1016/j.chemosphere.2013.04.097subject
Has Abstractpub_date
2013-09-01 00:00:00pages
115-22issue
1eissn
0045-6535issn
1879-1298pii
S0045-6535(13)00722-4journal_volume
93pub_type
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