Abstract:
:Two dimeric steroidal terephthalates derived from epimeric 4,5-seco-cholest-3-yn-5-ols were prepared starting from cholesterol in a five-step synthetic sequence. X-ray crystallography shows that the obtained compounds display novel supramolecular networks in the solid state in which the facial hydrophobicity of the steroidal skeletons plays an important role. Unambiguous NMR characterization of the obtained dimers is also provided.
journal_name
Steroidsjournal_title
Steroidsauthors
Alarcón-Manjarrez C,Arcos-Ramos R,Álamo MF,Iglesias-Arteaga MAdoi
10.1016/j.steroids.2016.03.001subject
Has Abstractpub_date
2016-05-01 00:00:00pages
66-72eissn
0039-128Xissn
1878-5867pii
S0039-128X(16)00059-3journal_volume
109pub_type
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