Stabilization of arsenic sludge with mechanochemically modified zero valent iron.

Abstract:

:Modified zero valent iron (ZVI) is obtained from commercial iron powder co-ground with manganese dioxide (MnO2) in intensive mechanical stress. The result indicates that the modified ZVI is very effective in arsenic sludge stabilization with a declination of arsenic leaching contraction from 72.50 mg/L to 0.62 mg/L, much lower than that of ordinary ZVI (10.48 mg/L). The involved process, including mechanochemical activation, corrosion and arsenic adsorption, is characterized explicitly to verify the improved arsenic stabilization mechanism. It shows that the mechanically formed Fe-Mn binary oxides layer results in an intensive corrosion extent, generating a mass of corrosion products. Moreover, as the emergence of Mn will restrain the process of iron (hydr)oxides crystallization, the ultimate corrosion products of the modified ZVI predominates in amorphous iron (hydr)oxides, performing much better in arsenic absorption. According to the BCR analysis, unstable arsenic in sludge is easily transformed to residual fraction by the help of amorphous iron (hydr)oxides, resulting in a restrained environmental availability of arsenic sludge after the modified ZVI stabilization.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Liang Y,Min X,Chai L,Wang M,Liyang W,Pan Q,Okido M

doi

10.1016/j.chemosphere.2016.10.087

subject

Has Abstract

pub_date

2017-02-01 00:00:00

pages

1142-1151

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(16)31469-2

journal_volume

168

pub_type

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