Fast assessment of bioaccessible metallic contamination in marine sediments.

Abstract:

:A fast (16min) procedure to assess the bioaccessible metallic fraction of Cd, Cr, Cu, Ni, Pb and Zn simultaneously extracted (SEM) from marine sediments plus an indirect approach to determine acid volatile sulfides (AVS) are presented. For the extraction process magnetic agitation was compared with ultrasonic stirring (using a bath and a probe), and several stirring times were assayed. The proposed SEM procedure uses an ultrasonic probe and 1mL of HCl. It dramatically minimizes the turnaround time and the residues. AVS were evaluated as the difference between the amounts of sulphur in the solid residue after the extraction and total sulphur in the original sample. These procedures are fast, easy to implement and cost-effective to assess the potential risk posed by metals in marine sediments. They were tested using several CRMs and applied to sediments from two Galician Rias (NW Spain); their SEM-AVS differences indicated no biological risk.

journal_name

Mar Pollut Bull

authors

Terán-Baamonde J,Carlosena A,Soto-Ferreiro RM,Andrade JM,Prada D

doi

10.1016/j.marpolbul.2017.08.033

subject

Has Abstract

pub_date

2017-12-15 00:00:00

pages

310-317

issue

1-2

eissn

0025-326X

issn

1879-3363

pii

S0025-326X(17)30703-8

journal_volume

125

pub_type

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